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Synthesis and structure of the product of bis-condensation of 4-methyl-2,6-diformylphenol with dimethyl N′,N′-hydrazine diacetate

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Abstract

Bis-condensation of 4-methyl-2,6-diformylphenol with dimethyl N′,N′-hydrazine diacetate gave product I. The structure of I was determined by X-ray analysis. The conformations of the two side chains of dimethyl N′,N′-hydrazine diacetate are significantly different. The position of one chain is fixed by the intramolecular H-bond of O−H.…N type. Due to its conformation, compound I is partly ready for complex formation with d-metals.

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Authors
  1. V. Kh. Kravtsov
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  2. V. I. Lozan
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  3. Yu. A. Simonov
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  4. O. A. Bologa
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  5. N. V. Gerbeleu
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  6. T. I. Malinovskii
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Additional information

Institute of Applied Physics, Academy of Sciences, Moldova Republic. Institute of Chemistry, Academy of Sciences, Moldova Republic. Translated fromZhurnal Struktumoi Khimii, Vol. 35, No. 3, pp. 91–98, May–June, 1994.

Translated by L. Smolina

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Kravtsov, V.K., Lozan, V.I., Simonov, Y.A. et al. Synthesis and structure of the product of bis-condensation of 4-methyl-2,6-diformylphenol with dimethyl N′,N′-hydrazine diacetate. J Struct Chem 35, 358–363 (1994). https://doi.org/10.1007/BF02578289

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  • DOI: https://doi.org/10.1007/BF02578289

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