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Synthesis, X-ray diffraction study, and crystal structure analysis of novel copper Alkoxy-β-diketonates: bis(6,2-dimethyl-6-methoxy-3,5-heptanedionato) copper(II) and bis(1-phenyl-4-methyl-4-methoxy-1,3-pentanedionato) copper(II)

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Abstract

This article is a continuation of the structural study of Cu(II) complexes with alkoxy-β-diketones [1]. Alkoxy-β-diketones, possessing the same complexing ability as classical β-diketones, are more accessible and inexpensive ligands. In some properties (e.g., volatility), metal complexes with these ligands are closely related to metal β-diketonates and can effectively replace them in some important coating methods, including the MOCVD method.

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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 6, pp. 169–175, November–December, 1994.

Translated by T. Yudanova

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Baidina, I.A., Gromilov, S.A., Stabnikov, P.A. et al. Synthesis, X-ray diffraction study, and crystal structure analysis of novel copper Alkoxy-β-diketonates: bis(6,2-dimethyl-6-methoxy-3,5-heptanedionato) copper(II) and bis(1-phenyl-4-methyl-4-methoxy-1,3-pentanedionato) copper(II). J Struct Chem 35, 899–905 (1994). https://doi.org/10.1007/BF02578123

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  • DOI: https://doi.org/10.1007/BF02578123

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