Skip to main content
SpringerLink
Log in

Synthesis, properties, and structure of intercalated graphite fluosulfonate fluorides

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Graphite fluosulfonate fluorides of the composition C2Fx−y(SO3F)y (x+y≈1) have been synthesized. The new compounds can be treated as derivatives of graphite fluorides C2Fx(x≈1) in which approximately 1/50 of the F atoms have been replaced by SO3F groups. The intercalates based on the new matrices have been studied by X-ray phase analysis, IR spectroscopy, mass spectrometry, and thermography. The ability of the intercalates to absorb various substances is investigated. It is shown that the introduction of a few SO3F groups into the C2Fx matrices significantly changes the physicochemical properties and the structure of intercalates; in particular, for intercalates of stage II structure this expands the scope of substances that can penetrate into interlayer spacings. The dependence of the penetration ability of the substances on the van der Waals sizes of their molecules makes intercalates resemble zeolites in properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. F. Yudanov and I. I. Yakovlev,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,1, 66–69 (1988).

    Google Scholar 

  2. N. F. Yudanov and L. I. Chernyavskii,Zh. Strukt. Khim.,28, No. 4, 86–95 (1987).

    CAS  Google Scholar 

  3. N. F. Yudanov, I. I. Chernyavskii, V. I. Lisoivan, and I. I. Yakovlev,ibid.,29, No. 3, 78–83 (1988).

    CAS  Google Scholar 

  4. N. F. Yudanov, E. A. Ukraintseva, L. I. Chernyavskii, and I. I. Yakovlev,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,3, 30–34 (1989).

    Google Scholar 

  5. N. F. Yudanov, E. G. Boguslavskii, I. I. Yakovlev, and S. P. Gabuda,Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 272–276 (1988).

    Google Scholar 

  6. A. M. Panich and N. F. Yudanov,Zh. Strukt. Khim.,32, No. 2, 79–83 (1991).

    CAS  Google Scholar 

  7. V. G. Makotchenko, A. S. Nazarov, G. S. Yuriev, and I. I. Yakovlev,Zh. Neorg. Khim.,36, No. 8, 1950–1955 (1991).

    CAS  Google Scholar 

  8. V. I. Lisoivan, S. A. Gromilov, and N. F. Yudanov,Zavod. Lab.,52, No. 3, 36–38 (1986).

    Google Scholar 

  9. K. S. Krasnov (ed.),Molecular Constants of Inorganic Compounds [in Russian], Khimiya, Leningrad (1979), p. 394.

    Google Scholar 

  10. Yu. S. Diakonov, “Development of a direct method for solving mixed-layered structures,” inCrystal Chemistry and Structure of Minerals [in Russian], Nauka Leningrad (1974), p. 33.

    Google Scholar 

  11. V. A. Drits and B. A. Sakharov,X-Ray Diffraction Analysis of Mixed-Layered Minerals [in Russian], Nauka, Moscow (1976).

    Google Scholar 

Download references

Authors
  1. N. F. Yudanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. N. Chekhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Lisoivan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Mikheev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. I. Yakovlev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, Novosibirsk. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No, 1, pp. 144–151, January–February, 1995

Translated by I. Izvekova

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yudanov, N.F., Chekhova, G.N., Lisoivan, V.I. et al. Synthesis, properties, and structure of intercalated graphite fluosulfonate fluorides. J Struct Chem 36, 126–132 (1995). https://doi.org/10.1007/BF02577759

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02577759

Keywords

Search

Navigation