Skip to main content
SpringerLink
Log in

Synthesis and X-ray analysis of (RS)-N-tert-butyl-2-anilino-

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The crystal and molecular structure of (RS)-N-Tert-butyl-2-anilino-3,3-dimethylbutanamide, a derivative of an amino acid that was obtained by highly selective cleavage of 1,3-di-tert-butylaziridinone by aniline, is described. The racemic mixture of the amide crystallizes in the space groupP 21/n with four molecules per unit cell. Crystal Data:a=10.483(2) Å,b=6.206(1) Å,c=24.767(5) Å,β=90.39(3),V=1611.5(6) A3,R(F)[I>2σ(I)]=0.0679.wR(F 2) [I>2σ(I)]=0.1148.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lengyel, I.: Sheehan, J.C.Angew. Chem. Int. Ed. Engl. 1968,25.

  2. L'abbe, G.Angew. Chem. Int. Ed. Engl. 1980,276.

  3. Talaty, E.R.: Dupuy, A.E., Jr.: Utermochlen, C.M.J. Chem. Soc. Chem. Comm. 1971.

  4. Yusoff, M.M.; Talaty, E.R.,Tetrahedron Lett. 1996,37, 8695.

    Article  CAS  Google Scholar 

  5. MSC (1990) CTR (4:0:9). Program for AFC5 X-ray diffractometer control, Molecular Structures Corp. Woodlands, TX.

    Google Scholar 

  6. MSC (1990) PROCESS (TEXSAN 5.0). Program for reduction of data collected on Rigaku AFC5 diffractometers. Molecular Structures Corp. Woodlands, TX.

    Google Scholar 

  7. Sheldrick, G.SHEIXS-86. Program for Crystal Structure Solution: Institut for Anorganische Chemie der Universitat: Tammanstrasse 4. D-3400 Göttingen: Germany. 1986.

    Google Scholar 

  8. Sheldrick, G.SHELXL-93. Program for Crystal Structure Refinement: Institut fur Anorganische Chemie der Universitat, Tammanstrasse 4. D-3400 Göttingen: Germany.

  9. International Tables for Crystallography. Vol C: Wilson. A.J.C. Ed.: Kluwer Academic Publishers. Dordecht: Tables 4.2.6.8 (pp 219–222) and 6.1.1.4 pp 500–502.

  10. Allen, F.H.; Kennard, O.Chem. Design Automat. News 1993,8, 31.

    Google Scholar 

  11. Spek, A.L.PLATON. Program for Crystal Structure Results Analysis: Vakgroep Algemene Chemie. University of Utrecht. Afdeling Kristal-En Structurchemie. Padualaan 8. 3584 Ch Utrecht. The Netherlands.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Texas A & M University, 77845, College Station, Texas

    Joseph H. Reibenspies

  2. Department of Chemistry, Wichita State University, 67260-0051, Wichita, Kansas

    Erach R. Talaty & Mashitah M. Yusoff

Authors
  1. Joseph H. Reibenspies
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Erach R. Talaty
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mashitah M. Yusoff
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Reibenspies, J.H., Talaty, E.R. & Yusoff, M.M. Synthesis and X-ray analysis of (RS)-N-tert-butyl-2-anilino-. J Chem Crystallogr 27, 727–730 (1997). https://doi.org/10.1007/BF02576552

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02576552

Key Words

Search

Navigation