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Crystal structures of polymeric complexes of zinc(II) bromide and perchlorate with 1,4-diazoniabicyclo [2.2.2]octane-1,4-diacetate

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Abstract

Two zinc(II) complexes containing a flexible double betaine, namely [{Zn(L)Br2}n]·nH2O (1) and [{Zn(L)2(H2O)2}n](ClO4)2n·4nH2O (2) [L=1,4-diazoniabicyclo [2.2.2]octane-1,4-diacetate,−O2CCH2N+(CH2CH2)3N+CH2CO2 −], have been prepared and shown to have polymeric structures by single-crystal X-ray analysis. Complex (1) exhibits an infinite zigzag chain in which each zinc(II) atom is coordinated by two unidentate carboxylate oxygen atoms and two bromide ligands in a distorted tetrahedral geometry. Complex (2) consists of an assembly of catonic Zn(L)2(H2O)2 2+ moieties and discrete perchlorate anions as well as lattice water molecules. In (2) each zinc(II) atom is coordinated by two pairs of unidentate carboxylate oxygen atoms and two aqua ligands in a distorted octahedral geometry and cross-linked by skeletons of double betaine ligands to form a corrugated layer structure corresponding to the plane (100).

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Author notes

  1. Ping-Rong Wei

    Present address: Department of Chemistry, Zhengzhou University, Zhengzhou, P.R. China

  2. Bo-Mu Wu

    Present address: Institute of Biophysics, Beijing, P.R. China

Authors and Affiliations

  1. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong

    De-Dong Wu

  2. Institute of Biophysics, Beijing, P.R. China

    Thomas C. W. Mak

  3. Department of Chemistry, Peking University, P.R. China, Beijing

    Ze-Ying Zhang

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  1. Ping-Rong Wei
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  2. De-Dong Wu
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  4. Ze-Ying Zhang
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  5. Thomas C. W. Mak
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Wei, PR., Wu, DD., Wu, BM. et al. Crystal structures of polymeric complexes of zinc(II) bromide and perchlorate with 1,4-diazoniabicyclo [2.2.2]octane-1,4-diacetate. J Chem Crystallogr 27, 609–615 (1997). https://doi.org/10.1007/BF02576460

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  • DOI: https://doi.org/10.1007/BF02576460

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