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X-ray diffraction studies oncis-[Ru(bpy)2(PMe3)Cl+][ClO4 −] andcis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO4 −]; two ordered structures in thecis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

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Abstract

The complexcis-[Ru(bpy)2(PMe3)Cl+][ClO4 −] crystallizes in space group P21/c andcis-[Ru(bpy)2{PMe2(o-tol)]Cl+][ClO4 −] crystallizes in space group\(P\bar 1\); each is present as a racemate and neither structure suffers from disorder. The Ru−PMe2(o-tol) bond length of 2.324(2)Å is slightly longer than the simple Ru−PMe3 bond length of 2.310(2) Å.

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Authors and Affiliations

  1. Department of Chemistry, University at Buffalo, State University of New York, North Campus, 14260-3000, Buffalo, New York

    Melvyn Rowen Churchill, Lynn M. Krajkowski, My Hang Vo Huynh & Kenneth J. Takeuchi

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  1. Melvyn Rowen Churchill
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  2. Lynn M. Krajkowski
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  3. My Hang Vo Huynh
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  4. Kenneth J. Takeuchi
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Churchill, M.R., Krajkowski, L.M., Vo Huynh, M.H. et al. X-ray diffraction studies oncis-[Ru(bpy)2(PMe3)Cl+][ClO4 −] andcis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO4 −]; two ordered structures in thecis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series. J Chem Crystallogr 27, 589–597 (1997). https://doi.org/10.1007/BF02576457

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  • DOI: https://doi.org/10.1007/BF02576457

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