Abstract
A unique 2-amino-1,2,3-triazole system has been synthesized by the reaction of avicinal diazide with triphenylphosphine. The crystal structures of five 2-amino-1,2,3-triazole systems, a ditetrazole and a Staudinger adduct are reported.Ab initio calculations are used to rationalize the structures and properties of these materials, and possible reaction pathways are discussed.
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Sun, D., Krawiec, M., Campana, C.F. et al. 2-Amino-1,2,3-triazole derivatives fromvicinal diazides. J Chem Crystallogr 27, 577–588 (1997). https://doi.org/10.1007/BF02576456
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DOI: https://doi.org/10.1007/BF02576456