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[NaBi(EDTA)(H2O)3]n: synthesis, crystal structure, and thermal behavior

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The synthesis and crystal structure of the EDTA complex [NaBi(EDTA)(H2O)3]n are reported. It crystallizes in the monoclinic crystal system (space groupP21/c,a=6.822(1)Å,b=16.733(6)Å,c=13.763(2)Å, β=97.13(2)°). Bi(EDTA) entities are connected through carboxylate bridges resulting in layers parallel to the (010) plane. These layers are strongly linked by Na carboxylate and Na−OH2 bridging interactions, establishing short Bi−Na and Na−Na distances. Pyrolysis of this complex under sulfur vapor between 600 and 900°C leads to the mixed sulfide NaBiS2. Pyrolysis in air shows a very complicated decomposition mechanism and the probable formation of a bimetallic oxycarbonate.

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  1. CEMES/CNRS, 29 rue Marvig, 31055, Toulouse Cedex, France

    Joël Jaud, Bertrand Marrot, Chantal Brouca-Cabarrecq & Alain Mosset

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  1. Joël Jaud
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  2. Bertrand Marrot
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  3. Chantal Brouca-Cabarrecq
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  4. Alain Mosset
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Jaud, J., Marrot, B., Brouca-Cabarrecq, C. et al. [NaBi(EDTA)(H2O)3]n: synthesis, crystal structure, and thermal behavior. J Chem Crystallogr 27, 109–117 (1997). https://doi.org/10.1007/BF02575903

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  • DOI: https://doi.org/10.1007/BF02575903

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