Abstract
Data are presented which enable binary diffusion coefficients and their concentration dependences to be predicted from diffusion coefficients and thermal diffusion factors at 300 K. The results up to 2000 K are compared with corresponding values derived from the complication of Mason and Marrero.
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A. E. Humphreys and E. Mason,Phys. Fluids 13:65 (1970).
P. J. Dunlop and C. M. Bignell,J. Chem. Phys. 102:5781 (1995).
P. J. Dunlop and C. M. Bignell,J. Chem. Phys. 104:296 (1996).
E. A. Mason and T. R. Marrero, inAdvances in Atomic and Molecular Physics, Vol. 6, (Academic Press, New York, 1970), p. 155.
E. A. Mason,J. Chem. Phys. 27:75, 782 (1957).
M. F. Laranjeira,Physica 26:409, 417 (1960).
W. A. Oost, J. Los, H. Cauwenbergh, and W. van Dael,Physica 62:409 (1972).
J. Kestin, S. T. Ro, and W. A. Wakeham,Trans. Faraday Soc. 67:2308 (1971).
J. Kestin, S. T. Ro, and W. A. Wakeham,Chem. Soc. Faraday Trans. 68:2316 (1972).
P. J. Dunlop,J. Chem. Phys. 100:3149 (1994).
G. C. Maitland, M. Rigby, E. B. Smith, and W. A. Wakeham,Intermolecular Forces (Clarendon, Oxford, 1981).
M. Keil, L. J. Danielson, and P. J. Dunlop,J. Chem. Phys. 94:296 (1991).
P. S. Arora, H. L. Robjohns, and P. J. Dunlop,Physica 95A:561 (1979).
R. D. Trengove, H. L. Robjohns, T. N. Bell, M. L. Martin, and P. J. Dunlop,Physica 108A:488 (1981).
R. D. Trengove and P. J. Dunlop,Proceedings 8th International Symposium on Thermophysical Properties, J. V. Sengers, ed. (ASME, New York, 1981) Vol. I, p. 289.
R. D. Trengove and P. J. Dunlop,Ber. Bunsenges Phys. Chem. 86:628 (1982).
R. D. Trengove and P. J. Dunlop,Physica 115A:339 (1982).
R. D. Trengove, H. L. Robjohns and P. J. Dunlop,Ber. Bunsenges Phys. Chem. 87:1187 (1983).
R. D. Trengove, H. L. Robjohns, and P. J. Dunlop,Ber. Bunsenges Phys. Chem. 88:450 (1984).
P. J. Dunlop and C. M. Bignell, unpublished results.
P. J. Dunlop, C. M. Bignell, W. L. Taylor, and B. A. Meyer,J. Chem. Phys. 87: 3591 (1987).
W. L. Taylor, J. J. Hurly, B. A. Meyer, and P. J. Dunlop,J. Chem. Phys. 103: 6959 (1995)
P. J. Dunlop and C. M. Bignell,Ber. Bunsenges Phys. Chem. 99:77 (1995).
R. D. Trengove, H. L. Robjohns, M. L. Martin, and P. J. Dunlop,Physica 108A: 502 (1981).
R. D. Trengove, H. L. Robjohns, and P. J. Dunlop,Physica 128A:486 (1984).
P. J. Dunlop and C. M. Bignell,Physica 167:628 (1990).
P. J. Dunlop, C. M. Bignell, and T. N. Bell,J. Chem. Phys. 94:6211 (1991).
R. D. Trengove, H. L. Robjohns, and P. J. Dunlop,Ber. Bunsenges Phys. Chem. 86:951 (1982).
P. J. Dunlop and C. M. Bignell,J. Chem. Phys. 105:3219 (1996).
P. J. Dunlop and C. M. Bignell,J. Chem. Phys. 93:2701 (1990).
P. J. Dunlop and C. M. Bignell,J. Chem. Phys. 97:5638 (1992).
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Paper dedicated to Professor Edward A. Mason.
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Dunlop, P.J., Bignell, C.M. Prediction of the temperature dependence of binary diffusion coefficients of gaseous systems from thermal diffusion factors and diffusion coefficients at 300 K. Int J Thermophys 18, 939–945 (1997). https://doi.org/10.1007/BF02575239
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DOI: https://doi.org/10.1007/BF02575239