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Thermochemistry of heteroatomic compounds

VII. Enthalpies of solution, vaporization and solvation of three-coordinated arsenic derivatives

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Abstract

The enthalpies of vaporization of different classes three-coordinated arsenic compounds have been determined according to their enthalpies of solution in hexane and molar refraction. The enthalpies of solvation of cyclic and acyclic As(III)-derivatives in hexane, carbon tetrachloride,p-xylene and pyridine are obtained and discussed.

Zusammenfassung

Entsprechend ihrer Lösungsenthalpien in Hexan und ihrer Molrefraktionen wurden die Verdampfungsenthalpien verschiedener Klassen trikoordinierter As(III)-verbindungen ermittelt. Die Solvatationsenthalpien von cyclischen und acyclischen As(III)-verbindungen in Hexan, Tetrachlorkohlenstoff,p-Xylol und Pyridin wurden ermittelt und diskutiert.

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Authors and Affiliations

  1. Kazan Construction Engineers Institute, Zelionaya str. 1, 420043, Kazan, Tatarstan

    V. V. Ovchinnikov, T. B. Makeeva & L. I. Lapteva

  2. Kazan State Technological University, Tolstoy str. 68, 420015, Kazan, Tatarstan

    V. A. Valiullina & L. M. Pilishkina

  3. Institute of Organic and Physical Chemistry of Russian Academy of Sciences, Arbusov str. 8, 420083, Tatarstan, Kazan, Russian Federation

    A. I. Konovalov

Authors
  1. V. V. Ovchinnikov
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  2. T. B. Makeeva
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  3. L. I. Lapteva
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  4. V. A. Valiullina
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  5. L. M. Pilishkina
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  6. A. I. Konovalov
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Additional information

Part 6, see Ref. [1].

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Ovchinnikov, V.V., Makeeva, T.B., Lapteva, L.I. et al. Thermochemistry of heteroatomic compounds. Journal of Thermal Analysis 45, 735–739 (1995). https://doi.org/10.1007/BF02548889

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  • DOI: https://doi.org/10.1007/BF02548889

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