Abstract
An enormous amount of detailed information can be obtained concerning macromolecules in aqueous solution using data obtained from differential scanning and titration microcalorimetry. This claim is supported by reference to examples taken from recent work concerned with micelles (e.g. CTAB), vesicles (e.g. DOAB and DDP) and enzymes (e.g. CAT and DNA gyrase).
Zusammenfassung
Durch Einsatz von Angaben aus DS- und Titrationsmikrokalorimetrie kann ein erheblicher Umfang an Informationen über Makromoleküle in wäßrigen Lösungen erhalten werden. Diese Behauptung wird durch Bezugnahme auf Beispiele aus jüngsten Arbeiten über Mizellen, Bläschen und Enzyme bestätigt.
Similar content being viewed by others
References
J. M. Sturtevant, Ann. Rev. Phys. Chem., 38 (1987) 463.
M. J. Blandamer, B. Briggs, J. Burgess, P. M. Cullis and G. Eaton, J. Chem. Soc., Faraday Trans., 87 (1991) 1169.
T. Wiseman, S. Williston, J. F. Brandts and L.-N. Lin, Analytical Biochemistry, 179 (1989) 131.
R. W. Gurney, Ionic Processes in Solution, McGraw-Hill, New York 1953.
M. J. Blandamer, M. D. Butt and P. M. Cullis, Thermochim. Acta, 211 (1992) 49.
M. A. Gallardo-Jimenez and T. H. Lilley, J. Chem. Soc., Faraday Trans., 85 (1989) 2909 (and references therein).
G. C. Kresheck, Water—A Comprehensive Treatise (ed. F. Franks) Plenum Press, New York, 1993, Vol. 4, Chapter 2.
J. H. Clint, Surfactant Aggregates, Blackie, Glasgow 1992.
Y. Mori, Micelles, Plenum Press, New York, 1992.
N. M. van Os, J. R. Haak and L. A. M. Rupet, Physico-Chemical Properties of Selected Anionic, Cationic and Nonionic Surfactants, Elsevier, Amsterdam 1993.
M. T. Bashford and E. M. Woolley, J. Phys. Chem., 89 (1985) 3173.
M. J. Blandamer, P. M. Cullis, L. G. Soldi, A. Kacperska and M. C. S. Subha, unpublished work.
K. S. Pitzer, Activity Coefficients in Electrolyte Solutions (ed. R. M. Pytkowicz), C.R.C. Press, Boca Raton, Florida 1979, Vol. I, Chapter 7.
J. Ananthaswamy and G. Atkinson, J. Chem. Eng. Data, 29 (1984) 81.
C. Treiner, Chem. Soc. Reviews 23 (1994) 349.
J. Bach, M. J. Blandamer, J. Burgess, P. M. Cullis, A. Kacperska, P. Tran, K. C. Rao, L. G. Soldi and M. C. S. Subha, J. Phys. Org. Chem., 8 (1995) 108.
M. J. Blandamer, B. Briggs, M.D. Butt, P. M. Cullis, L. Gorse and J. B. F. N. Engberts, J. Chem. Soc., Faraday Trans., 88 (1992) 2871.
M. J. Blandamer, J. Burgess and J. M. W. Scott, J. Chem. Soc., Faraday Trans., 80 (1984) 2881.
T. Kunitake, Angew. Chem. Int. Ed., 31 (1992) 709.
M. J. Blandamer, B. Briggs, P. M. Cullis, J. A. Green, M. Waters, J. B. F. N. Engberts and D. Hoekstra, J. Chem. Soc. Faraday Trans., 88 (1992) 3431.
M. J. Blandamer, B. Briggs, M. D. Butt, P. M. Cullis, M. Waters, J. B. F. N. Engberts and D. Hoekstra, J. Chem. Soc., Faraday Trans., 90 (1994) 727.
W. V. Shaw and A. G. W. Leslie, Ann. Rev. Biophys. Chem., 20 (1991) 363.
C. Kleanthous, P. M. Cullis and W. V. Shaw, Biochem., 24 (1985) 5307 (and references therein).
M. J. Blandamer, B. Briggs, P. M. Cullis, A. P. Jackson, A. Maxwell and R. J. Reece, Biochemistry, 33 (1994) 7510.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Blandamer, M.J., Cullis, P.M. & Engberts, J.B.F.N. Differential scanning and titration calorimetric studies of macromolecules in aqueous solution. Journal of Thermal Analysis 45, 599–613 (1995). https://doi.org/10.1007/BF02548875
Issue Date:
DOI: https://doi.org/10.1007/BF02548875