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Solid-phase reaction kinetics

Meaningful kinetic constantsvs. formal parameters

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Abstract

It is argued that, for the macroscopic parameters of conventional kinetic models to become meaningful, they may be and must be expressed in terms of elementary single-barrier processes. To accomplish this means to associate some (external) extensional measure with a single-barrier elementary act, remaining within the logic of the existing geometrical-probabilistic scheme. A manner of doing this involving the use of Dirichlet fragmentations is suggested.

Zusammenfassung

Es ist umstritten, ob makroskopische Parameter herkömmlicher kinetischer Modelle sinnvoll sind und ob sie in Ausdrücken von Elementarprozessen dargestellt werden können bzw. müssen. Dies zu erreichen bedeutet, einige erweiterte Messungen mit Elementarereignissen zu verbinden und dabei innerhalb der Logistik von existierenden Schemen geometrischer Wahrscheinlichkeit zu bleiben. Hierzu wird eine Methode unter Einbeziehung von Dirichlet-Fragmentationen vorgeschlagen.

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Authors and Affiliations

  1. Kharkov University, P.O. Box 10313, 310023, Kharkov, Ukraine

    A. Korobov

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  1. A. Korobov
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Korobov, A. Solid-phase reaction kinetics. Journal of Thermal Analysis 44, 187–196 (1995). https://doi.org/10.1007/BF02547147

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  • DOI: https://doi.org/10.1007/BF02547147

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