Abstract
Practical detersive systems are inherently complicated, involving multiphase multicomponent soils adherent to a substrate, immersed in a multicomponent bath. Detergency is therefore not a simple colloidal effect, but the result of a large number of colloidal effects occurring simultaneously, each at its characteristic rate. To consider such systems meaningfully they are first resolved into a series of simpler model systems, each of which can usually be arranged to consist of three homogenous phases. Cleaning is the net result of the transitions of these model systems between the agglomerated (adherent) and the dispersed (separated) states. These transitions can be described and predicted in terms of well established, generally accepted concepts of modern colloid science. The resolution of typical detersive systems into their simple constituent models and the mechanisms of soil separation in these models are illustrated and discussed.
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References
Adam, N.K., J.Soc. Dyers Colour, 53:121 (1937).
Kling, W., E. Langer and I. Haussner, Melliand Textilber. 25:198 (1945).
Buras, E.M., Jr., C.F. Goldthwait and R.M. Kraemer, Text. Res. J. 20:239 (1950). I.J. Gruntfest, O.B. Hager and H.B. Walker, Am. Dyest. Rep. 36:225 (1947).
Shinoda, K., Editor “Solvent Properties of Surfactant Solutions,” Marcel Dekker, New York, 1967.
Prince, L.M., J. Soc. Cosmetic Chem. 21:193 (1970). J.H. Schulman, W. Stoeckenius and L.M. Prince, J. Phys. Chem. 63:1677 (1959).
Harris, J.C., and W.H. Yanko, ASTM Bull. 158:49 (1949).
Fort, T., Jr., H.R. Billica and T.H. Grindstaff, Text. Res. J. 36:99 (1966).
Gordon, B.E., W.T. Shebs and R.U. Bonnar, JAOCS 44:711 (1967).
Gordon, B.E., J. Roddewig and W.T. Shebs, Ibid. 44:289 (1967).
Schott, H., Text. Res. J. 39:296 (1966).
Lambert, J.M., and H.L. Sanders, Ind. Eng. Chem. 42:1388 (1950).
Powe, W.C., Text. Res. J. 29:879 (1959).
Derjaguin, B., and L. Laudau, Acta Physicochem. USSR 14:633 (1941). See also B. Derjaguin, Disc. Faraday Soc. 18:85 (1954).
Verwey, E.J.W., and J. Th. G. Overbeek, “Theory of the Stability of Lyophobic Colloids,” Elsevier, Amsterdam, 1948.
Langbein, D., J. Adhes. 1:237 (1969).
Napper, D.H., Ind. Eng. Chem. Prod. Res. Dev. 9:467 (1970).
Smith, W.H., M. Wentz and A.R. Martin, JAOCS 45:83 (1968); J.W. Hensley, Ibid. 42:993 (1965).
Blake, T.D., and J.M. Haynes, J. Colloid Interface Sci. 30:421 (1969).
Bacon, O.C., and J.E. Smith, Ind. Eng. Chem. 40:2361 (1948).
Tuzson, J., and B.A. Short, Text. Res. J. 30:989 (1960). L. Loeb and R.O. Shuck, JAOCS 46:299 (1969).
Krupp, H., Advan. Colloid Interface Sci. 1:208 (1967).
Kling, W., Fette Seifen Anstrichm. 69:676 (1967).
Schwartz, A.M., Ind. Eng. Chem. 61:10 (1969).
Rader, C.A., and A.M. Schwartz, Text. Res. J. 32:140 (1962).
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Schwartz, A.M. Recent advances in detergency theory. J Am Oil Chem Soc 48, 566–570 (1971). https://doi.org/10.1007/BF02544564
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DOI: https://doi.org/10.1007/BF02544564