Abstract
The prediction of the vapor-liquid equilibria of vegetable oil-hexane mixtures is studied. Activity coefficients are calculated by the UNIFAC model. Different entropic contributions to activity coefficients from the literature are analyzed. These modifications improve the performance of the original UNIFAC model in vapor-liquid equilibrium calculations.
Similar content being viewed by others
References
Tsonopoulos, C.,AIChE J., 20:263 (1974).
Fredenslund, Aa., R.L. Jones and J.M. Prausnitz,21:1086 (1975).
Pollard, E.F., H.C.E., Vix and D.A. Gastrock,IEC 37:1022 (1945).
Smith, A.S., and F.J. Wechter,J. Am. Oil Chem. Soc. 27:381 (1950).
Lebert, A., and D. Richon,J. Food Sci. 49:1301 (1984).
Fredenslund, Aa., J. Gmehling and P. Rasmussen,Vapor-Liquid Equilibria using UNIFAC, Elsevier, Amsterdam, 1977.
Bailey, A.E.,Industrial Oil and Fat Products Interscience Publishers, Inc., New York, 1951.
Kikic, I., P. Alessi, P. Rasmussen and Aa. Fredenslund,Can. J. Chem. Eng. 58:253 (1980).
Oishi, T., and J.M. Prausnitz,IEC Pros. Des. Dev. 17:333 (1978).
Beret, S., and J.M. Prausnitz,AIChE J. 21:1123 (1975).
Elbro, H.S., Aa. Fredenslund and P. Rasmussen,AIChE Meeting, Washington, D.C., November 1988.
Bondi, A.,Physical Properties of Molecular Crystals, Liquids and Glasses, Wiley & Sons, New York, 1968.
Author information
Authors and Affiliations
About this article
Cite this article
Fornari, T., Bottini, S. & Brignole, E.A. Application of UNIFAC to vegetable oil-alkane mixtures. J Am Oil Chem Soc 71, 391–395 (1994). https://doi.org/10.1007/BF02540519
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02540519