Abstract
The increasing use of active chlorinecontaining compounds in machine dishwashing has led to the need for chlorine-stable, low foaming detergent formulations. To avoid oxidative degradation of nonionic surfactant and simultaneous loss of available chlorine, a new basic formulation process has been devised. This obviates the need for modifying nonionic surfactants. The process requires a preferred order of addition and the use of tetrasodium pyrophosphate builder as an integral part of the composition. The detergent product is free-flowing, granular, readily soluble and exhibits no tendency to cake on storage. A suggested machine dishwashing formulation is given, and data are presented which show good chlorine stability and excellent dishwashing performance.
Similar content being viewed by others
References
U.S. Dept. of Commerce, “Statistical Abstract of the United States,” 88th Annual Edition, 1967, p. 776.
Wall Street Journal, February 8, 1968, p. 1.
McNeil, E., E. A. Choper and R. R. Banville, Soap and Chemical Specialties,41(9), 125–137 (1965).
Schmolka, I. R., and T. M. Kaneko, “Protein Soil Defoaming in Machine Dishwashers,” AOCS 41st Meeting Chicago, October 1967.
Gray, F. W., V. J. Richter and R. C. Odioso, JAOCS,44, 725–727 (1967).
Roth, E. S., J. S. Thompson and R. R. Keast, Soap and Chemical Specialties,43(12), 66 (1967).
Dupre, J., R. E. Wolfram and D. R. Fordyce, Ibid.36(2), 55–58; (3), 55–56 (1960).
Niederhauser, W. D., and E. J. Smialkowski (Rohm and Haas Co.), U.S. 2,856,434 (1958).
General Aniline and Film Corp., Netherlands 6,505,065 (1965).
Boettner, F. E., and R. M. Ross (Rohm and Haas Co.), U.S. 3,281,475 (1966).
Killam, H. S., and N. A. Leister (Rohm and Haas Co.), France 1,395,977 (1963).
Mansfield, R. C., and J. Dupre (Rohm and Haas Co.), U.S. 3,310,496 (1967).
Guthrie, D. W., (Petrolite Corp.), U.S. 3,356,612 (1967).
Keast, R. R., and D. S. Corliss (FMC Corp.), British 1,090,166 (1967).
Kaneko, T. M., and I. R. Schmolka (Wyandotte Chemicals Corp.), U.S. 3,359,207 (1967).
Milenkovich, J. A., and J. E. Henjum (Procter and Gamble Co.), U.S. 2,895,916 (1959).
Podas, W. M., and S. B. Crecelius, “Latest Developments in Automatic Dishwashing,” 53rd Meeting of the International Association of Milk, Food and Environmental Sanitarians, Minneapolis, August 1966.
Oberle, T. M. (Economics Laboratory, Inc.), U.S. 3,306,858 (1967).
NEMA Standard, “Washing Ability of Household Electric Dishwashers,” Publication HS 1, 1964, p. 3.
Author information
Authors and Affiliations
About this article
Cite this article
Kaneko, T.M., Schmolka, I.R. & Compton, J.W. Chlorine-stable machine dishwashing products. J Am Oil Chem Soc 45, 855–858 (1968). https://doi.org/10.1007/BF02540169
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02540169