Abstract
Nitrosyl chloride was added to methyl oleate on a preparative scale to give the adduct in essentially quantitative yield. The chlorine of the adduct was quite labile; was replaced by methoxyl, hydroxyl, acetoxyl, piperidino, and amino groups; and was eliminated to give the unsaturated nitroso compound. Under any conditions only 15–20% of the nitroso group of the adduct isomerized to oximino. Reduction with zinc and acetic acid gave the hydroxylamino derivative
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No. Utiliz. Res. and Dev. Div., ARS, USDA.
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Miller, W.R., Pryde, E.H., Cowan, J.C. et al. Nitrosyl chloride adduct of methyl oleate. J Am Oil Chem Soc 42, 713–716 (1965). https://doi.org/10.1007/BF02540045
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DOI: https://doi.org/10.1007/BF02540045