Abstract
We study the composition of the gel fraction, water absorption, and impedance characteristics of epoxy coatings modified with petroleum polymeric resin treated with maleic anhydride. It is shown that modified epoxy coatings are characterized by higher water resistance and better protective properties in acid media. We determine the optimal amount of the petroleum polymeric modifier and demonstrate the possibility of improvement of the corrosion resistance of modified epoxy coatings by subsequent thermal treatment.
Similar content being viewed by others
References
H. Lee and K. Neville,Handbook of Epoxy Resins [Russian translation], Énergiya, Moscow (1973).
M. I. Finkel'shtein,Industrial Application of Epoxy Paintwork Materials [in Russian], Khimiya, Leningrad (1983).
V. S. Aliev and N. B. Al'tman,Synthetic Resins Produced of Crude Petroleum [in Russian], Khimiya, Leningrad (1965).
A. D. Berents, A. B. Vol'-Épshtein, T. N. Mukhina, and G. L. Averkh,Processing of Liquid Products of Pyrolysis [in Russian], Khimiya, Moscow (1985).
Yu. V. Dumskii, G. F. Cherednikova, N. A. Kuznetsova, and M. E. Belyakov, “Synthesis of modified petroleum resins,”Kauchuk Rezina, No. 5, 30–32 (1988).
M. V. Pokhmurs'ka, I. M. Zin', I. M. Bilyi, and T. V. Humenets'kyi, “New protective composite coatings based on epoxy and aromatic petroleum resins,” in:Proceedings of the 4th Polish Conf. on Corrosion “Corrosion-93”, Warsaw (1993), pp. 167–170.
A. A. Blagonravova and A. I. Nepomnyashchii,Lacquer Epoxy Resins [in Russian], Khimiya, Moscow (1970).
L. N. Pirozhnaya, “Investigation of the process of curing of epoxy resins with maleic anhydride,”Plast. Massy, No. 6, 56–60 (1961).
M. F. Sorokin and L. G. Shodé, “Curing of epoxy resins with anhydrides of carboxylic acids in the presence of tertiary amines,”Lakokras. Mater. Ikh Primen., No. 2, 76–81 (1968).
R. M. Livshits, G. V. Rudnaya, G. I. Stanchenko, et al., “Analysis of the composition of “Piroplast-2” petroleum polymeric resin,”Lakokras. Mater. Ikh Primen., No. 2, 11–12 (1986).
A. D. Yakovlev,Chemistry and Technology of Paintwork Coatings [in Russian], Khimiya, Leningrad (1989).
G. Ya. Vorob'eva,Chemical Resistance of Polymeric Materials [in Russian], Khimiya, MOscow (1981).
G. W. Walter, “The application of impedance spectroscopy to study the uptake of sodium chloride solution in painted metals,”Corros. Sci.,32, No. 10, 1041–1058 (1991).
G. W. Walter, “The application of impedance methods to study the effects of water uptake and chloride ion concentration on the degradation of paints films. 1. Attached films,”Corros. Sci.,32, No. 10, 1059–1084 (1991).
I. L. Rozenfel'd and F. I. Rubinshtein,Anticorrosive Primers and Inhibited Paintwork Coatings [in Russian], Khimiya, Moscow (1980).
S. Ya. Selektor and V. P. Lapshin, “Investigation of the protective properties of paintwork coatings by e electrochemical methods,”Lakokkras. Mater. Ikh Primen., No. 5, 40–43 (1987).
Additional information
Karpenko Physicomechanical Institute, Ukrainian Academy of Sciences, L'viv. Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 32, No. 4, pp. 81–85, July–August, 1996.
Rights and permissions
About this article
Cite this article
Pokhmurs'kyi, V.I., Zin', I.M., Humenets'kyi, T.V. et al. Properties of epoxy-amine coatings modified with petroleum polymeric resins. Mater Sci 32, 470–475 (1996). https://doi.org/10.1007/BF02538973
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02538973