Abstract
The structures of three new sterols isolated fromGynostemma pentaphyllum (Cucurbitaceae) have been shown by chemical and spectroscopic methods to be 24,24-dimethyl-5α-cholest-7-en-3β-ol, (22E)-24,24-dimethyl-5α-cholesta-7,22-dien-3β-ol and 24,24-dimethyl-5α-cholesta-7,25-dien-3β-ol.
Similar content being viewed by others
References
Takemoto, T., Arihara, S., Yoshikawa, K., Hino, K., Nakajima, T., and Okuhira, M. (1984)Yakugaku Zasshi 104, 1155–1162.
Akihisa, T., Thakur, S., Rosenstein, F.U., and Matsumoto, T. (1986)Lipids 21, 39–47.
Knights, B.A. (1967)J. Gas Chromatogr. 5, 273–282.
Massey, I.J., and Djerassi, C., (1979)J. Org. Chem. 44, 2448–2456.
Hui, W.H., Luk, K., Arthur, H.R., and Loo, S.N. (1971)J. Chem. Soc. (C), 2826–2829.
Li, L.N., and Djerassi, C. (1981)J. Am. Chem. Soc. 103, 3606–3608.
Itoh, T., Sica, D., and Djerassi, C. (1983)J. Chem. Soc. Perkin Trans. I, 147–153.
Itoh, T., and Djerassi, C. (1983)J. Am. Chem. Soc. 105, 4407–4416.
Li, L.N., and Djerassi, C. (1981)Tetrahedron Lett. 22, 4639–4641.
Li, X., and Djerassi, C. (1983)Tetrahedron Lett. 24, 665–668.
Ritchie, E., Senior, R.G., and Taylor, W.C. (1969)Aust. J. Chem. 22, 2371–2387.
Lockley, W.J.S., Roberts, D.P., Rees, H.H., and Goodwin, T.W. (1973)Tetrahedron Lett., 3773–3776.
Nes, W.R., and McKean, M.L. (1977)Biochemistry of Steroids and Other Isopentenoids, University Park Press, Baltimore, MD.
Itoh, T., and Matsumoto, T. (1978)Yukagaku, 27, 745–756.
Author information
Authors and Affiliations
About this article
Cite this article
Akihisa, T., Shimizu, N., Tamura, T. et al. Structures of three new 24,24-dimethyl-Δ7-sterols fromGynostemma pentaphyllumfromGynostemma pentaphyllum . Lipids 21, 515–517 (1986). https://doi.org/10.1007/BF02535639
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02535639