Abstract
The low resolution mass spectra of 5,6-monoepoxyretinoic acid, 5,8-monoepoxyretinoic acid, 5,6-monoepoxyretinyl acetate, 5,8-monoepoxyretinyl acetate, 5,8-monoepoxyretinal, trimethylsilyl-5,6-monoepoxyretinoate, trimethylsilyl-5,8-monoepoxyretinoate, methyl-5,6-monoepoxyretinoate, methyl-5,8-monoepoxyretinoate, β-C19-retinal and β-C19-retinyl acetate-analogs of vitamin A—are presented. Characteristic features of the spectra are discussed. In addition, high resolution mass measurements are presented for six fragment ions of all-trans-retinoic acid and eleven fragment ions of methyl-5,6-monoepoxyretinoate.
Similar content being viewed by others
References
Nelson, E.C., M. Mayberry, R. Reid and K.V. John, Biochem. J. 121:731 (1971).
Nelson, E.C., B.A. Dehority and H.S. Teague, Anal. Biochem. 11:418 (1965).
Krishnamurthy, S., J.G. Bieri and E.L. Andrews, J. Nutr. 79:503 (1963).
Yagishita, K., P.R. Sundaresan and G. Wolf, Nature 203:410 (1964).
Zile, M., and H.F. DeLuca, Biochem. J. 97:180 (1965).
Roberts, A.B., and H.F. DeLuca, J. Lipid Res. 9:501 (1968).
Lippel, K., D.R. Manyan and A. Llewellyn, Arch. Biochem. Biophys. 139:421 (1970).
Wolf, G., J.G. Bergan and P.R. Sundaresan, Biochim. Biophys. Acta 69:524 (1963).
Zile, M., R.J. Emerick and H.F. DeLuca, Ibid. 141:639 (1967).
Olson, J.A., Amer. J. Clin. Nutr. 22:953 (1969).
Lehman, D., Ph.D. dissertation, Oklahoma State University, 1971.
Vecchi, M., W. Vetter, W. Walther, S.F. Jermstad and G.W. Schutt, Helv. Chimica Acta 50:1243 (1967).
Lin, R.L., G.R. Waller, E.D. Mitchell, K.S. Yang and E.C. Nelson, Anal. Biochem. 35:435 (1970).
John K.V., M.R. Lakshmanan and H.R. Cama, Biochem. J. 103:539 (1967).
Biemann, K., “Mass Spectrometry: Organic Chemical Applications,” McGraw-Hill Book Company, Inc., New York, 1962, p. 339.
Enzell, C.R., R.A. Appleton and I. Wahlberg, in “Biochemical Applications of Mass Spectrometry,” Edited by G.R. Waller, Wiley Interscience, New York, 1972, p. 375.
Thomas, A.F., and B. Willhalm, Tetrahedron Lett. 50:5129 (1967).
Baldas, J., Q.N. Porter, L. Cholnoky, J. Szaboles and B.C.L. Weedon, Chem. Comm. 23:852 (1966).
Author information
Authors and Affiliations
Additional information
Journal Article 2525, Oklahoma Agricultural Experiment Station, Stillwater, Okla.
These data were taken in part from a thesis submitted by the senior author in partial fulfillment of the requirement for the M.Sc., Oklahoma State University, July 1972.
About this article
Cite this article
Reid, R., Nelson, E.C., Mitchell, E.D. et al. Mass spectral analysis of eleven analogs of vitamin A1 . Lipids 8, 558–565 (1973). https://doi.org/10.1007/BF02532712
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02532712