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Isolation of a pure isomer of linoleic acid hydroperoxide

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Lipids

Abstract

A mixture of positional isomers of linoleic acid hydroperoxide was produced from the oxidation of linoleic acid by lipoxygenase from corn or soybean. Chromatography on a column of silicic acid separated 13-hydroperoxy-11,9-octadecadienoic acid in 99+% purity from the mixture obtained by soybean lipoxygenase oxidation of linoleic acid. Attempts at isolation of pure 9-hydroperoxy-10,12-octadecadienoic acid from hydroperoxides obtained by corn lipoxygenase oxygenation of linoleic acid were partially successful with isolation of the 9-hydroperoxide in 97% purity.

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Authors and Affiliations

  1. Northern Regional Research Laboratory, 61604, Peoria, Illinois

    H. W. Gardner

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  1. H. W. Gardner
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ARS, USDA.

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Gardner, H.W. Isolation of a pure isomer of linoleic acid hydroperoxide. Lipids 10, 248–252 (1975). https://doi.org/10.1007/BF02532488

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  • DOI: https://doi.org/10.1007/BF02532488

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