Abstract
In mixtures of 1,2- and 1,3-diglycerides stored some degrees below their melting points, a rather rapid isomerization of almost all the 1,2- diglycerides to the 1,3-isomers occurred. This solid-phase isomerization leads to a substantial increase in the yield of saturated and unsaturated mono- and mixed-acid 1,3-diglycerides.
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References
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De Groot, W.T.M. Acyl migration solid phase isomerization of 1,2-diglycerides to 1,3-isomers. Lipids 7, 626–628 (1972). https://doi.org/10.1007/BF02531967
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DOI: https://doi.org/10.1007/BF02531967