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Lipids

, Volume 6, Issue 6, pp 421–425 | Cite as

The infrared spectra and polymorphism of long chain esters: IV. Some esters from tetradecanol, hexadecanol, octadecanol, eicosanol, docosanol and dodecanoic, tetradecanoic, hexadecanoic, octadecanoic and eicosanoic acid

  • S. Aleby
  • I. Fischmeister
  • B. T. R. Iyengar
Article

Abstract

Infrared spectra and x-ray diffraction photographs have been recorded for some normal-chain esters of long chain acids and long chain alcohols. The substances show no polymorphism but two different structure types exist, one with the chains tilting towards the end group planes and one with vertical chains. The IR spectra permit determination of the chain length of the acid methylene chain. The length of the alcohol chain cannot be deduced.

Keywords

Hexadecyl Tetradecyl Octadecanoate Vertical Chain Tetradecanoate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Aleby, S., and I. Fischmeister, Arkiv kemi 31:267 (1969).Google Scholar
  2. 2.
    Aleby, S., and I. Fischmeister, Ibid. 31:283 (1969).Google Scholar
  3. 3.
    Aleby, S., and I. Fischmeister, Ibid. 31:291 (1969).Google Scholar
  4. 4.
    Aleby, S., Abstr. Gothenburg Diss Sci. 13 (1969).Google Scholar
  5. 5.
    Kreger, D.R., and C. Schamhart, Biochem. Biophys. Acta 19:22 (1956).PubMedCrossRefGoogle Scholar
  6. 6.
    Lutz, D.A., C.R. Eddy, and J.J. Hunter, Lipids 2:204 (1967).PubMedGoogle Scholar
  7. 7.
    Kohlhaas, R. Zeitschr. Krist. 98:418 (1938).Google Scholar
  8. 8.
    Crowe, R.W., and C.P. Smyth, J. Amer. Chem. Soc. 73:5401 (1951).CrossRefGoogle Scholar
  9. 9.
    Crowe, R.W., J.D. Hoffman, and C.P. Smyth, J. Chem. Phys. 20:550 (1952).CrossRefGoogle Scholar
  10. 10.
    Arnold, J.W., and R.J. Meakins, Trans. Faraday Soc. 51:1667 (1955).CrossRefGoogle Scholar
  11. 11.
    Dryden, J.S., and H.K. Welsh, Ibid. 60:2135 (1964).CrossRefGoogle Scholar
  12. 12.
    Hunter, J., and C.R. Eddy, JAOCS 44:341 (1967).Google Scholar
  13. 13.
    Iyengar, B.T.R., and H. Schlenk, Lipids 4:28 (1969).PubMedGoogle Scholar
  14. 14.
    Stenhagen, E., Acta Chem. Scand. 5:805 (1951).Google Scholar
  15. 15.
    Fischmeister, I, and K. Nilsson, Arkiv kemi 16:347 (1960).Google Scholar
  16. 16.
    Larsson, K., Acta Chem. Scand. 20:2255 (1966).PubMedGoogle Scholar
  17. 17.
    Aleby, S., and E. von Sydow, Acta Cryst. 13:487 (1960).CrossRefGoogle Scholar
  18. 18.
    Aleby, S., Acta Chem. Scand. 22:811 (1968).Google Scholar
  19. 19.
    Aleby, S., Ibid. 22:3146 (1968).CrossRefGoogle Scholar
  20. 20.
    Susi, H., and A. Jahn, JAOCS 43:479 (1966).Google Scholar
  21. 21.
    Susi, H., and S. Pazner, Spectrochim. Acta 18:499 (1962).CrossRefGoogle Scholar
  22. 22.
    Dinh-Nguyen, Ng., and I. Fischmeister, Arkiv kemi 32:181 (1970).Google Scholar
  23. 23.
    Jones, R.N., A.F. McKay, and R.G. Sinclair, J. Amer. Chem. Soc. 74:2575 (1952).CrossRefGoogle Scholar
  24. 24.
    Holland, R.F., and J.R. Nielsen, J. Mol. Spectrosc. 9:436 (1962).CrossRefGoogle Scholar
  25. 25.
    Wieser, H., W.G. Laidlaw, P.J. Krueger, and H. Fuhrer Spectrochim. Acta 24A:1055 (1968).Google Scholar

Copyright information

© American Oil Chemists’ Society 1971

Authors and Affiliations

  • S. Aleby
    • 1
  • I. Fischmeister
    • 2
  • B. T. R. Iyengar
    • 3
  1. 1.Crystallography Group, Medical Research Council Unit for Molecular Structure AnalysisUniversity of GoteborgGoteborgSweden
  2. 2.Institute of Medical BiochemistryUniversity of GoteborgGoteborgSweden
  3. 3.The Hormel InstituteAustin

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