Abstract
Deuterium labeled monoacid triglycerides were synthesized and their mass spectra were measured. The spectra provided further support for proposed (1) structures of principal ions, knowledge about the formation of [M-18]+, the interexchange of hydrogen atoms between 2 and the 5,6 or 7 positions and the explusion of part of the alkyl chain.
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Aasen, A.J., Lauer, W.M. & Holman, R.T. Mass spectrometry of triglycerides: II. Specifically deuterated triglycerides and elucidation of fragmentation mechanisms. Lipids 5, 869–877 (1970). https://doi.org/10.1007/BF02531118
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DOI: https://doi.org/10.1007/BF02531118