Journal of Radioanalytical Chemistry

, Volume 78, Issue 2, pp 247–253 | Cite as

Kinetic and analytical study on precipitation reactions with110AgNO3 of some di (β-chloroethyl) amine derivates and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers from dimethylformamide-water solution

  • AL. Cecal
  • V. Sunel
  • L. Ghimiciu
Article

Abstract

The kinetics of precipitation reactions with110AgNO3 of some di (β-chlorethyl) amine derivates and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers in dimethylformamide-water mixture, were studied. The rate constants of these reactions were of the order of 10−4 1 · mol−1 · min−1. The concentrations of the corresponding hydrochloride solutions were measured by radiometric titration with110AgNO3 solution of given concentration.

Keywords

Benzoyl Hydroxyethyl Silver Nitrate AgBr Precipitation Reaction 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. HAISSINSKY, La chime nucléaire et ses applications, Masson et Cie editeurs, Paris, 1957.Google Scholar
  2. 2.
    S. ARONOFF, Techniques of Radiobiochemistry, The Iowa State College Press, Iowa, 1958.Google Scholar
  3. 3.
    M. B. NEIMAN, D. GÁL, The Kinetick Isotope Method and its Application, Akadémiai Kiadó, Budapest, 1971.Google Scholar
  4. 4.
    F. DUTKA, D. GÁL, Intern. J. Appl. Radiation Isotopes, 13 (1962) 27.CrossRefGoogle Scholar
  5. 5.
    F. DUTKA, D. GÁL, Intern. J. Appl. Radiation Isotopes, 13 (1962) 35.CrossRefGoogle Scholar
  6. 6.
    D. GÁL, L. GUCZI, in Radioisotopes in the Physical Science and Industry, IAEA, Vienna, 1962.Google Scholar
  7. 7.
    I. P. SKIBIDA, Z. K. MAIZUS, N. M. EMANUEL, Dokl. Akad. Nauk SSSR, 146 (1962) 170.Google Scholar
  8. 8.
    I. P. SKIBIDA, Z. I. KULITSKI, Z. K. MAIZUS, Dokl. Akad. Nauk SSSR, 148 (1963) 1358.Google Scholar
  9. 9.
    I. P. SKIBIDA, E. M. GONIKBERG, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk. (1964) 286.Google Scholar
  10. 10.
    A. LANGER, J. Phys. Chem., 45 (1941) 639.CrossRefGoogle Scholar
  11. 11.
    L. HERFORTH, H. KOCH, Radiophysikalisches und radiochemisches Grundprakticum, VEB Deutscher Verlag der Wissenschaften, Berlin, 1962.Google Scholar
  12. 12.
    J. TÖLGYESSY, V. JESENAK, T. BRAUN, Radiochemical Methods of Analysis, IAEA, Vienna, 1965.Google Scholar
  13. 13.
    T. BRAUN, J. TÖLGYESSY, Radiometric Titrations, Pergamon Press, Oxford, 1967.Google Scholar
  14. 14.
    T. NĂŞCUŢIU, Metode radiochimice de analiza, Editura Academiei RSR, Bucareşti, 1973.Google Scholar
  15. 15.
    K. KIMURA, F. KAMETANI, Japan Analyst, 10 (1961) 1293.Google Scholar
  16. 16.
    J. TÖLGYESSY, S. VARGA, Chem. Zvesti, 17 (1963) 779.Google Scholar
  17. 17.
    T. BRAUN, Chim. Anal., 46 (1964) 61.Google Scholar
  18. 18.
    T. BRAUN, I. MAXIM, I. GĂLĂŢÊANU, Zhur. Anal. Khim. 14 (1959) 542.Google Scholar
  19. 19.
    I. GĂLĂŢÊANU, Radiochimie aplicată, Editura Academiei RSR, Bucuresti, 1976.Google Scholar
  20. 20.
    I. M. KORENMAN, F. R. SEYANOVA, H. M. MEZINA, M. I.OSTASEVA, Zhur. Anal. Khim., 12 (1957) 48.Google Scholar
  21. 21.
    V. SUNEL, C. H. BUDEANU, I. MAZILU, M. AOSTOLESCU, Bul. Inst. Politehnic Iasi, 25 (1979) 85.Google Scholar
  22. 22.
    V. SUNEL, Al. CECAL, Rev. Chim., in print.Google Scholar
  23. 23.
    V. SUNEL, M. APOSTOLESCU, C. H. BUDEANU, D. DĂNET, Rev. Chim., in print.Google Scholar
  24. 24.
    I. G. MURGULESCU, E. SEGAL, T. OONCESCU, Introducere în Chimia Fizică, Vol. II, 2, Editura Academiei RSR, Bucuresti, 1981.Google Scholar

Copyright information

© Akadémiai Kiadó 1983

Authors and Affiliations

  • AL. Cecal
    • 1
  • V. Sunel
    • 1
  • L. Ghimiciu
    • 1
  1. 1.Faculty of Chemical TechnologyPolytechnic Institute of IasiIasi(Romania)

Personalised recommendations