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Correlation between structure and catalytic activity of manganese oxides in liquid-phase oxidation of 1-octene

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Abstract

We have studied the correlation between the crystal structure and the catalytic activity of manganese oxides MnO, MnO2, Mn3O4, and Mn2O3 in liquid-phase oxidation of 1-octene by molecular oxygen. The catalytic activity decreases in the series of oxides with octahedral coordination environment for the manganese atoms MnO−Mn2O3−MnO2. The oxide Mn3O4 (with mixed tetrahedral and octahedral environment for the Mn atoms) catalyzes the process according to a different mechanism.

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Authors
  1. M. G. Kotur
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L'vov Polytechnic State University, 12 S. Bandery ul., L'vov-13 290646, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 34, No. 5, pp. 324–327, September–October, 1998.

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Kotur, M.G. Correlation between structure and catalytic activity of manganese oxides in liquid-phase oxidation of 1-octene. Theor Exp Chem 34, 297–300 (1998). https://doi.org/10.1007/BF02523266

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  • DOI: https://doi.org/10.1007/BF02523266

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