Abstract
A new variant of the kinetic distributive method was used to study the kinetics of the oxidation of ethylene by PdCl2 complexes supported on silica gel taking account of the equilibrium distribution of ethylene between the gas phase, silica gel, and metal complex reaction sites. Mono-, bi-, and polynuclear palladium(II) species are found to participate in the reaction. The PdII activity increases with increasing amount of nuclei in the species.
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L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Lyuksemburg ul., Donetsk 83114, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 36, No. 4, pp. 243–246, July–August, 2000.
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Tret'yakov, V.P., Rudakov, E.S., Min'ko, L.A. et al. Adsorption and kinetics of the oxidation of ethylene on PdCl2/SiO2 . Theor Exp Chem 36, 224–227 (2000). https://doi.org/10.1007/BF02522756
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DOI: https://doi.org/10.1007/BF02522756