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Reactivity of inorganic α-nucleophiles in the transfer of phosphoryl and phosphonyl groups

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Abstract

The kinetic behavior of inorganic α-nucleophiles (NH2O−, HOO−, ClO−, BrO−, and F− ions) in the transfer of phosphoryl and phosphonyl groups was studied. It was shown that ClO− and BrO− ions are unique α-nucleophiles, exhibiting not only supernucleophilic characteristics but also high oxidizing activity. The undoubted leaders among inorganic nucleophiles are the HOO− ion and hydroxylamine. The latter cleaves substrates that are stable in water unusually quickly not only in alkaline but also in neutral and acidic media.

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Authors
  1. A. F. Popov
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  2. T. M. Prokop'eva
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  3. I. P. Suprun
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  4. Yu. S. Simanenko
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Additional information

L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Lyuksemburg ul., Donetsk 83114, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 36, No. 4, pp. 226–232, July–August, 2000.

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Popov, A.F., Prokop'eva, T.M., Suprun, I.P. et al. Reactivity of inorganic α-nucleophiles in the transfer of phosphoryl and phosphonyl groups. Theor Exp Chem 36, 208–214 (2000). https://doi.org/10.1007/BF02522753

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  • DOI: https://doi.org/10.1007/BF02522753

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