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A study of gamma and neutron interaction with aqueous solutions of L-phenylalanine

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Abstract

A study of neutron and gamma interaction (in the low dose range) with L-phenylalanine in aqueous solutions shows that the main radiolytic pathway occurs through the attack of OH radicals. The products of the interaction are essentially tyrosine, Dopa and melanine in both cases. However, for gamma radiation there is a complete utilization of the OH radicals and the reaction pathway mainly proceeds by the sequence: phenylalanine»tyrosine»Dopa»melanine. On the contrary, for neutron radiation, the OH recombination is a rather efficient process and the prevailing pathway is: phenylalanine»Dopa»melanine.

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References

  1. A. R. ANDERSON, E. J. HART, Radiation Res., 14 (1961) 689.

    CAS  Google Scholar 

  2. J. W. BAUM, Proc. 2nd Symp. Microdosimetry, Stresa, Italy, H. G. EBERT (Ed.) EUR 4452. d-f-e, 1969, p. 653.

  3. C. A. BENASSI, E. SCOFFONE, G. GALIAZZO, G. JORI, Photochem. Photobiol., 6 (1976) 857.

    Article  Google Scholar 

  4. J. CHRYSOCHOOS, Radiation Res., 33 (1968) 465.

    CAS  Google Scholar 

  5. P. J. DYNE, J. M. KENNEDY, Can. J. Chem., 38 (1960) 61.

    Article  CAS  Google Scholar 

  6. B. HOGEWEG, G. W. BARENDSEN, Proc. 2nd Symp. Microdosimetry, Stresa, Italy, H. G. EBERT, (Ed.) EUR 4452 d-f-e, 1969, p. 171.

  7. A. KUPPERMANN, G. G. BELFORD, J. Chem. Phys., 36 (1962), p. 1427.

    Article  CAS  Google Scholar 

  8. J. LIEBSTER, J. KOPOLDOVA, Advances in Radiation Biology, L. G. AUGENSTEIN et al. (Eds.), Academic Press, New York, London, Vol. 1, 1964, p. 208.

    Google Scholar 

  9. R. A. NICOLAUS, Gazz. Chim. Ital., 85 (1955) 659.

    CAS  Google Scholar 

  10. R. A. NICOLAUS, Atti Accademia Nazionale dei Lincei, Roma, 1964, p. 292

  11. G. SCHOLES, P. SHAW, R. L. WILSON, Pulse Radiolysis, M. EBERT et al. (Eds), Academic Press, New York, London, 1965, p. 151.

    Google Scholar 

  12. E. STAHL, Dünnschicht-Chromatographie, Springer Verlag, Berlin, 1962, p. 503.

    Google Scholar 

  13. O. H. WHEELER, R. MONTALVO, Radiation Res., 40 (1969) 1.

    CAS  Google Scholar 

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Colautti, P., Moschini, G., Stievano, B.M. et al. A study of gamma and neutron interaction with aqueous solutions of L-phenylalanine. J. Radioanal. Chem. 34, 9–17 (1976). https://doi.org/10.1007/BF02521506

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