Skip to main content
Log in

Surface analysis with the aid of low-energy electrons

The case of semiconductor surfaces compared with other methods

  • Microtechniques
  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

A comparison is made between methods for surface analysis which use low-energy electron beams, and methods such as those using surface conductance and field effect. The distinction between these two groups of methods is relevant to the case of semiconductors. Surface conductance and field effect measurements have a high sensitivity, 108–1010 excess charges per cm2 near the surface being detectable, but they do not reveal the chemical composition of the surface. On the other hand, Auger electron spectroscopy (AES), which uses low-energy electrons, is less sensitive, 1012–1013 foreign atoms per cm2 being detectable, but this method is highly specific with respect to the sort of atoms (and in some cases molecules) present on the surface. A number of applications of AES are given. Another method, that of low-energy electron diffraction (LEED), can only be used for surfaces of single crystals. With LEED, values of repeat distances at the surface can be found. In some cases these are very sensitive to the concentrations of foreign atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. H. Brattain, J. Bardeen,Bell Syst Tech., J., 32 (1953) 1.

    Google Scholar 

  2. A. Many, Y. Goldstein, N. B. Grover, Semiconductor Surfaces, North-Holland, Amsterdam, 1965.

    Google Scholar 

  3. D. R. Frankl, Electrical Properties of Semiconductor Surfaces, Pergamon, Oxford, 1967.

    Google Scholar 

  4. L. A. Harris,J. Appl. Phys., 39 (1968) 1419.

    Article  CAS  Google Scholar 

  5. C. C. Chang,Surf. Sci., 25 (1971) 53 (a review).

    Article  CAS  Google Scholar 

  6. P. J. Estrup, E. G. McRae,Surf. Sci., 25 (1971) 1 (a review).

    Article  CAS  Google Scholar 

  7. D. P. Smith,Surf. Sci., 25 (1971) 171 (a review).

    Article  CAS  Google Scholar 

  8. A. Benninghoven, S. Storp,Z. Angew. Phys., 31 (1971) 31;A. Benninghoven,Z. Phys., 230 (1970) 403.

    CAS  Google Scholar 

  9. H. W. Werner, in Developments in Applied Spectroscopy, 7A (1969) 239.

  10. Z. Jurela, in Atomic Collisions Phenomena in Solids, North-Holland, Amsterdam, 1970, p. 339.

    Google Scholar 

  11. E. Schlegel,I.E.E.E. Trans. on Electron Devices, ED 14 (1967) 728; and ED 15 (1968) 951.

    CAS  Google Scholar 

  12. J. Bardeen, W. Shockley,Phys. Rev., 74 (1948) 230; 75 (1949) 203.J. Bardeen, W. H. Brattain Phys. Rev., 75 (1949) 1208.

    Article  Google Scholar 

  13. P. Handler, in Semiconductor Surface Physics (Kingston Ed.), Philadelphia, 1957, p. 23.

  14. R. E. Schlier, H. E. Farnsworth, in Semiconductor Surface Physics (Kingston, Ed.), Philadelphia, 1957, p. 3; andJ. Chem. Phys., 30 (1959) 917.

  15. C. J. Davisson, L. H. Germer,Phys. Rev., 30 (1927) 705.

    Article  CAS  Google Scholar 

  16. A. H. Boonstra,Philips Res. Repts. Suppl., 1968, No. 3.

  17. M. J. Sparnaay, J. van Ruler,Physica, 27 (1961) 153.

    Article  CAS  Google Scholar 

  18. M. J. Sparnaay,Surf. Sci., 13 (1969) 99.

    Article  CAS  Google Scholar 

  19. A. J. van Bommel, F. Meyer,Surf. Sci., 8 (1967) 467.

    Article  Google Scholar 

  20. A. J. van Bommel, F. Meyer,Surf. Sci., 8 (1967) 381.

    Article  Google Scholar 

  21. J. J. Lander, J. Morrison,J. Chem. Phys., 37 (1962) 729.

    Article  CAS  Google Scholar 

  22. R. M. Stern, J. J. Perry, D. S. Boudreaux,Rev. Mod Phys., 41 (1969) 275.

    Article  Google Scholar 

  23. H. Bethe,Ann. Physik., 87 (1928) 55.

    CAS  Google Scholar 

  24. M. B. Webb, M. G. Lagally, Lecture Notes Fifth Low-energy Electron Diffraction Seminar, Washington, D. C., 1971 (not published).

  25. J. J. Vrakking, F. Meyer,Appl. Phys. Lett., 18 (1971) 226.

    Article  CAS  Google Scholar 

  26. F. Meyer, E. E. de Kluizenaar, G. A. Bootsma,Surf. Sci., 27 (1971) 88;G. A. Bootsma, F. Meyer,Surf. Sci., 13 (1969) 14; 52 (1969) 110.

    Article  CAS  Google Scholar 

  27. B. A. Joyce, J. H. Neave,Surf. Sci., 27 (1971) 499.

    Article  CAS  Google Scholar 

  28. A. R. Miller, The Adsorption of Gases on Solids, Cambridge U.P., 1949, p. 64.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sparnaay, M.J. Surface analysis with the aid of low-energy electrons. J. Radioanal. Chem. 12, 101–114 (1972). https://doi.org/10.1007/BF02520980

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02520980

Keywords

Navigation