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Radiohochspannungsionophoretische Untersuchungen der Isotopenaustauschreaktionen zwischen Polythionaten, Thiosulfat und Sulfit

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Abstract

The isotopic exchange of35S between thiosulfate/sulfite and tetrathionate/thiosulfate is examined. The kinetic data are determined. In both cases the reactions are of second order. As the isotopic exchange between tetrathionate/thiosulfate is very fast, these reaction components are used in high dilution. Furthermore, the extent of exchange during the separation is determined.

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Authors and Affiliations

  1. Fachrichtung Anorganische Analytik und Radiochemie der Universität des Saarlandes, 6600, Saarbrücken, BRD

    H. Wagner & H. Schreier

Authors
  1. H. Wagner
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  2. H. Schreier
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Wagner, H., Schreier, H. Radiohochspannungsionophoretische Untersuchungen der Isotopenaustauschreaktionen zwischen Polythionaten, Thiosulfat und Sulfit. J. Radioanal. Chem. 42, 75–83 (1978). https://doi.org/10.1007/BF02520627

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  • DOI: https://doi.org/10.1007/BF02520627

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