Abstract
With the exception of the formation of coordinatively saturated adducts, synergic extractions using chelating extractants are reviewed. Emphasis is laid on less common synergic systems. These include the formation of adducts containing also inorganic anions, extraction of chelates in the presence of bulky organic cations, influence of various anions on the extraction of chelates, the use of acidic synergic agents, extraction with two chelating agents, and some other systems.
Similar content being viewed by others
References
H. M. N. H. IRVING, in Solvent Extraction Chemistry, Proc. Int. Conf., D. DYRSSEN, J. O. LILJENZIN, J. RYDBERG, (Eds.), North Holland, Amsterdam, 1967, p. 91.
T. V. HEALY, Synergistic Adducts as Coordination Compounds, Report AERE—R 5941. 1968.
Y. MARCUS, A. S. KERTES, Ion Exchange and Solvent Extraction of Metal Complexes, Wiley, New York, 1969.
D. P. GRADDON, Coord. Chem. Rev., 4 (1969) 1.
J. HÁLA, Chemické Listy, 73 (1979) 225.
J. STARÝ, Anal. Chim. Acta, 28 (1963) 132.
F. Ch. CHOU, Q. FERNANDO, H. FREISER, Anal. Chem., 37 (1965) 361.
S. OKI, I. TERADA, Anal. Chim. Acta, 61 (1972) 49.
E. Ya. RAKOVSKII, B. L. SEREBRYANNYI, N. D. KLYUYEVA, Zh. Analit. Khim., 29 (1974) 1086.
E. SEKIDO, Y. YOSHIMURA, Y. MASUDA, J. Inorg. Nucl. Chem., 38 (1976) 1183.
S. OKI, I. TERADA, Anal. Chim. Acta, 66 (1973) 201.
C. WOODWARD, H. FREISER, Anal. Chem., 40 (1968) 345.
J. AGGETT, Chem. Ind. (London), (1967), 27.
J. AGGETT, J. Inorg. Nucl. Chem., 32. (1970) 2767.
H. IRVING, D. N. EDGIGTON, J. Inorg. Nucl. Chem., 20 (1961) 321; 21 (1961) 169.
J. G. CUNNINGHAM, P. SCARGILL, H. H. WILLIS Report AERE/C/M 215, 1954.
L. GENOV, G. KASALOV, Monatsch., 100 (1969) 594.
J. HÁLA, unpublished results.
J. HÁLA, J. Inorg. Nucl. Chem., 29 (1967) 187, 1317.
M. S. RAHAMAN, H. L. FINSTON, Anal. Chem., 40 (1968) 1709.
L. NEWMAN, P. KLOTZ, J. Phys. Chem., 67 (1963) 205.
L. NEWMAN, P. KLOTZ, Inorg. Chem., 5 (1966) 461; 11 (1972) 2150.
J. HÁLA, J. Less-Common Metals, 26 (1972) 117.
J. HÁLA, Coll. Czech. Chem. Commun., 38 (1973) 2588.
J. HÁLA, E. TÁBORSKÁ, Radiochem. Radional. Letters, 26 (1976) 229.
J. HÁLA, J. PŘÍHODA, Coll. Czech. Chem. Commun., 40 (1975) 546, 3617.
T. SEKINE, D. DYRSSEN, J. Inorg. Nucl. Chem., 26 (1964) 2013.
V. S. SHARMA, J. SCHUBERT, J. Chem. Ed., 46 (1969) 507.
L. NEWMAN, P. KLOTZ, Report BNL 10350, 1967.
M. SUNDERSANAN, A. K. SUNDARAM, Proc. Ind. Acad. Sci., A82 (1975) 77.
T. SHIGEMATSU, T. HONJYO, Bull. Chem. Soc. Japan, 43 (1970) 796.
T. SEKINE, D. DYRSSEN, J. Inorg. Nucl. Chem., 29 (1967) 1489.
Ch. WOO, W. F. WAGNER, D. E. SANDS, J. Inorg. Nucl. Chem., 34 (1972) 307.
T. SHIGEMATSU, M. TABUSHI, M. MATSUI, T. HONJYO, Bull. Chem. Soc. Japan, 42 (1969) 976.
D. S. FLETT, S. TITMUS, J. Inorg. Nucl. Chem., 31 (1969) 2612.
L. HUMMELSTEDT, H. E. SUND, J. KARJALUOTO, L. O. BERTS, B. G. NYMAN, Proc. Int. Solvent Extraction Conf., Vol. 1, Lyon, 1974, p. 829.
M. TANAKA, I. KOJIMA, J. Inorg. Nucl. Chem., 29 (1967) 1769.
M. NISHIMURA, S. NORIKI, S. MURAMOTO, Anal. Chim. Acta, 70 (1974) 121.
J. HÁLA, J. SMOLA, Radiochem. Radioanal. Letters, 34 (1978) 325.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hála, J. Some aspects of synergic extractions with chelating extractants. J. Radioanal. Chem. 51, 15–25 (1979). https://doi.org/10.1007/BF02519920
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02519920