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Ion exchange separation of different oxidation states of sulphur formed by35Cl(n, p)35S reaction in alkali halides

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Abstract

Studies on the distribution of various oxidation states of recoil sulphur formed by35Cl(n, p)35S reaction in the alkali halides, namely, NaCl, KCl and RbCl have been made. A suitable anion exchange method using Amberlite IRA-410 in the chloride form has been described for rapid separation of the various radiosulphur species. The elution was carried out by means of nitrate solutions. The observed results on the effect of cation environment in affecting the distribution of radioactive sulphur amongst its various oxidation states were discussed on the basis of electron affinity and ionic size of the metal ion in question.

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  1. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, 92, Acharya Prafulla Chandra Road, 700 009, Calcutta, India

    N. R. Das & S. N. Bhattacharyya

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  1. N. R. Das
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  2. S. N. Bhattacharyya
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Das, N.R., Bhattacharyya, S.N. Ion exchange separation of different oxidation states of sulphur formed by35Cl(n, p)35S reaction in alkali halides. J. Radioanal. Chem. 57, 61–67 (1980). https://doi.org/10.1007/BF02519865

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