Abstract
The effect of temperature on the extraction of the trivalent actinides Am3+, Cm3+ and Cf3+ with the liquid cation exchanger dinonylnaphthalenesulphonic acid (HD) in toluene is studied. The different thermodynamic functions of this system are determined from the experimental results. It is found that the free energy variation for the extraction of these metal ions by HD is mainly determined by the entropic terms arising from the hydration-dehydration process of the exchanged ions.
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Raieh, M.A., Aly, H.F. Thermodynamics of dinonylnaphthalene sulfonic acid (HD). J. Radioanal. Chem. 57, 17–21 (1980). https://doi.org/10.1007/BF02519859
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DOI: https://doi.org/10.1007/BF02519859