Abstract
The extraction of Pu(IV) from perchloric acid by HTTA—TPPO mixtures employing benzene and chloroform as diluents has been studied. While Pu(TTA)4·TPPO appears to be the dominant species with benzene, mixed adducts involving perchlorate ion formation seem to be predominant in the extraction with chloroform. The adduct formation between Pu(TTA)4 and different neutral donors, in benzene, was studied by spectrophotometry and the constants of the 1∶1 adducts formed were evaluated.
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Ramakrishna, V.V., Mapara, P.M. & Patil, S.K. Spectrophotometric studies on synergic extraction of Pu(IV) by HTTA—Neutral extractant mixtures. J. Radioanal. Chem. 78, 65–70 (1983). https://doi.org/10.1007/BF02519750
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DOI: https://doi.org/10.1007/BF02519750