Ceric phosphate as ion exchanger in the separation of carrier-free²¹⁰Bi from²¹⁰Pb,⁹⁰Y from⁹⁰Sr and UX₁ from u

Abstract

Separations of tracer cations in parent daughter systems such as carrier-free²¹⁰Bi from²¹⁰Pb,⁹⁰Y from⁹⁰Sr and UX₁ from U have been carried out in a column of ceric phosphate as ion exchanger. The exchanger has been prepared by mixing ceric sulfate in hot 10M orthophosphoric acid at 80°C and keeping for overnight. A pale yellow coloured precipitate was formed which was washed, dried at 70°C for 48 hours when a hard, granular variety suitable for column use, with a cerium to phosphate ratio of 1∶2 was obtained. 0.1M H₃PO₄ was used as medium in each of the systems studied. The β-decay curves of the separated²¹⁰Bi and⁹⁰Y and the γ-spectrum of UX₁ show that all these activities are radiochemically pure. The separation procedures adopted in each case were very clean and simple, gave quantitative yields and took less than half an hour.