Abstract
The effect of γ-rays on acidic and alkaline solutions of ethylenediaminetetraacetatocerium(III) has been studied both in the presence and absence of oxygen. A mechanism is proposed, in which the radiolytic degradation of the complex is due only to OH, while the radiolytic oxidation of Ce(III) EDTA to Ce(IV) by γ-rays occurs via the formation of hydrogen peroxide.
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References
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Hafez, M.B., Rouhdy, H. & Hafez, N. Radiolysis of aqueous solutions of ethylenediaminetetraacetatocerium(III). J. Radioanal. Chem. 43, 121–129 (1978). https://doi.org/10.1007/BF02519447
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DOI: https://doi.org/10.1007/BF02519447