Skip to main content
Log in

Liquid-liquid extraction behaviour of mercury(II) as bromide, iodide and thiocyanate

Separation from Zn(II), Cd(II), Tl(I), Tl(III) and Au(III)

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

The liquid-liquid extraction behaviour of mercury(II) as bromide, iodide and thiocyanate has been investigated in different oxygenated and non-oxygenated solvents. The effects of the molarity of acids, their sodium or potassium salts, the concentration of Hg(II) ions, the temperature and masking anions have been studied. The possibilities of separation of Hg(II) from Zn(II), Cd(II) Tl(I), Tl(II) and Au(III) in these extractions are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. K. Kim, J. Silverman,Anal. Chem., 37 (1965) 1616.

    Article  CAS  Google Scholar 

  2. R. Christell, J. G. Erwall, K. Ljunggren, B. S. Sjostrand, T. Westermark, Intern. Conf. on Modern Trends in Activation Analysis, A and M University, Texas, College Station, 1965, p. 380.

  3. L. A. Rancitelli, T. M. Tanner, J. M. Dean, USAEC Report BNWL-1051, Pt. 2, 1969, p. 142.

  4. R. Dams, J. A. Robbins, K. A. Rahn, J. W. Winchester,Anal. Chem., 42 (1970) 861.

    Article  CAS  Google Scholar 

  5. S. S. Brar, P. F. Gustafson,Trans. Am. Nucl. Soc., 12 (1969) 485.

    Google Scholar 

  6. G. W. Reed, K. Kigoshi, A. Turkevich,Geochim. Cosmochim. Acta, 20 (1960) 122.

    Article  Google Scholar 

  7. W. D. Ehmann, J. F. Lovering,Geochim. Cosmochim. Acta, 31 (1967) 357.

    Article  CAS  Google Scholar 

  8. S. N. Tandon, T. P. Kohman, USAEC Report NYO-844-71, 1966, p. 35.

  9. R. Bock, H. Kusche E. Bock,Z. Anal. Chem., 138 (1953) 167.

    Article  CAS  Google Scholar 

  10. R. Bock,Z. Anal. Chem., 133 (1951) 110.

    Article  CAS  Google Scholar 

  11. S. Kitahara,Bull. Inst. Phys. Chem. Res. (Tokyo), 24 (1948) 454.

    CAS  Google Scholar 

  12. H. M. Irving, F. J. C. Rosotti,Analyst, 77 (1952) 801.

    Article  CAS  Google Scholar 

  13. H. J. Moser, A. F. Voigt,J. Inorg. Nucl. Chem., 4 (1957) 354.

    Article  CAS  Google Scholar 

  14. S. N. Tandon, C. B. Gupta,Talanta, 18 (1971) 109.

    Article  CAS  Google Scholar 

  15. G. H. Morrison, H. Freiser, Solvent Extraction in Analytical Chemistry, Wiley, New York, 1957, pp. 129, 132, 134 and 136.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gupta, C.B., Tandon, S.N. Liquid-liquid extraction behaviour of mercury(II) as bromide, iodide and thiocyanate. J. Radioanal. Chem. 11, 59–66 (1972). https://doi.org/10.1007/BF02518618

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02518618

Keywords

Navigation