Skip to main content
Log in

A radiometric investigation of the precipitation of calcium fluoride

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

Errors arising from solubility losses and co-precipitation in the gravimetric determination of fluoride by precipitation of calcium fluoride by classical and homogeneous methods have been investigated by radiometric techniques. It is shown that co-precipitation of chloride is the larger source of error and least in the homogeneous method. Distribution of chloride in the calcium fluoride precipitate is shown to follow the Doerner-Hoskins distribution law.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. C. Thomas Jr., J. A. Sondel, R. C. Kerns,Internat. J. Appl. Radiat. and Isotopes, 16 (1965) 71.

    Article  CAS  Google Scholar 

  2. A. I. Vogel, A Text-book of Quantitative Inorganic Analysis, 3rd Ed, Longmans, London, p. 570, 1962.

    Google Scholar 

  3. B. W. Hoffman, S. B. Van Camerik,Anal. Chem, 39 (1967) 1198.

    Article  CAS  Google Scholar 

  4. G. Schwarzenbach, Complexometric Titrations, Methuen, London, 1957, p. 69.

    Google Scholar 

  5. L. Gordon, M. L. Salutsky, H. H. Willard, Precipitation from Homogeneous Solution, Wiley, New York, 1959, p. 124.

    Google Scholar 

  6. H. A. Doerner, W. M. Hoskins,J. Am. Chem. Soc., 47 (1925) 662.

    Article  CAS  Google Scholar 

  7. R. Geyer,Z. Anorg. Chem., 42 (1943) 252.

    Google Scholar 

  8. L. Gordon, M. C. Salutsky, H. H. Willard, ibid., p. 135. 42 (1943)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tcholakova, I., Whitley, J.E. A radiometric investigation of the precipitation of calcium fluoride. J. Radioanal. Chem. 2, 409–414 (1969). https://doi.org/10.1007/BF02518468

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02518468

Keywords

Navigation