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Photon activation analysis of trace metals in biological materials via collection of metal tropolone-5-sulfonate complexes onto anion-exchange resin

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Abstract

Tropolone-5-sulfonic acid was used to separate and collect trace elements as their complexes onto an anion-exchange resin in photon-activation of biological materials. Retention behaviour of the anionic complexes of Cr, Mn, Fe, Co, Ni, Cu, Zn, and Pb on Dowex 1-X8 resin was examined with respect to pH, amount of resin, concentration of the ligand, and coexisting salt anions, using radioisotope tracers. Under optimum conditions, Cr, Mn, Co, Ni, Zn and Pb were collected from the irradiated samples of NBS-SRM Orchard Leaves, NBS-SRM Spinach, green tea and black tea on the marcket. The analytical results agreed with certified values and the reproducibility was good.

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References

  1. V. VALKOVIĆ, Trace Element Analysis, Taylor & Francis Ltd., 1975, p. 86.

  2. M. ZIEF, J. W. MITCHELL, Contamination Control in Trace Element Analysis in Chemical Analysis, P. J. ELVING (Ed.), John Wiley & Sons, Inc. Canada, 1976, Vol. 47, Chapter 7.

    Google Scholar 

  3. T. E. GILLS, M. GALLORINI, H. L. ROOK, J. Radioanal. Chem., 46 (1978) 21.

    Article  CAS  Google Scholar 

  4. T. KATO, N. SATO, N. SUZUKI, Anal. Chim. Acta, 81 (1976) 337.

    Article  CAS  Google Scholar 

  5. N. SATO, T. KATO, N. SUZUKI, J. Radioanal. Chem., 36 (1977) 221.

    Article  CAS  Google Scholar 

  6. J. P. RILEY, D. TAYLOR, Anal. Chim. Acta, 40 (1968) 479.

    Article  CAS  Google Scholar 

  7. C. LEE, N. B. KIM, I. C. LEE, K. S. CHUNG, Talanta, 24 (1977) 241.

    Article  CAS  Google Scholar 

  8. C. BERGERIOUX, J. P. BLANC, W. HAERDI, J. Radianal. Chem., 37 (1977) 823.

    Article  CAS  Google Scholar 

  9. J. A. BUONO, R. W. KARIN, J. L. FASCHING, Anal. Chim. Acta, 80 (1975) 327.

    Article  CAS  Google Scholar 

  10. M. CIKUMA, A. HARADA, T. UEDA, S. YUBE, Talanta, 23 (1976) 489.

    Article  Google Scholar 

  11. K. S. LEE, W. LEE, D. W. LEE, Anal. Chem., 50 (1978) 255.

    Article  CAS  Google Scholar 

  12. J. E. GOING, G. WESENBERG, G. ANDREJAT, Anal. Chim. Acta, 81 (1976) 349.

    Article  CAS  Google Scholar 

  13. The Chemical Society London, Stability Constants Supplement No. 1, Alder Press, Oxford, 1971.

    Google Scholar 

  14. T. IKEMI, T. NOZOE, H. SUGIYAMA, Chem. Ind., (1060) 932.

  15. T. NOZOE, S. SETO, H. TAKEDA, S. MOROSAWA, K. MATSUMOTO, Proc. Japan Acad., 28 (1952) 192; and 27 (1951) 556.

    CAS  Google Scholar 

  16. T. NOZOE, S. SETO, T. IKEMI, T. ARAI, Proc. Japan Acad., 27 (1951) 24.

    CAS  Google Scholar 

  17. D. J. PIETRZYK, C. W. FRANK, Analytical Chemistry, 2nd ed., Academic Press, Inc., 1979, p. 560.

  18. K. FUWA, K. NOTSU, K. TSUNODA, H. KATO, Y. YAMAMOTO, K. OKAMOTO, Y. DOKIYA, S. TODA, Bull. Chem. Soc. Japan, 51 (1978) 1078.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan

    M. Yamashita & N. Suzuki

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  1. M. Yamashita
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  2. N. Suzuki
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Yamashita, M., Suzuki, N. Photon activation analysis of trace metals in biological materials via collection of metal tropolone-5-sulfonate complexes onto anion-exchange resin. J. Radioanal. Chem. 60, 73–85 (1980). https://doi.org/10.1007/BF02518285

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  • DOI: https://doi.org/10.1007/BF02518285

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