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Extractive separation of a lanthanum tracer from preparations on a calcium carrier obtained from steel samples

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Abstract

The separation of lanthanum from calcium and a number of radioisotopes of other elements by extraction with alkylphosphoric acids and tri-n-butylphosphate has been studied. A quantitative method has been developed for the separation of a lanthanum tracer from neutron-irradiated preparations on a calcium carrier, obtained from the steel-making process. This method improves the detectability of140La (from 5·10−7 to 10−10 g of La) by γ-ray spectrometry with a scintillation counter, and enables semiquantitative determination of lanthanum with a liquid GM tube, the error involved being about 100% for La contents >10−8 g, and about 30% for La contents >10−7 g.

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References

  1. E. Weźranowski, B. Rewieńska-Kościuk, E. Zarzecka, M. Radwan, Freiberger Forschungsh., B 141 (1969) 153.

    Google Scholar 

  2. B. Chodura, J. Michalik, T. S. Urbański, B. Rewieńska-Kościuk, M. Radwan, Paper presented at the meeting of the Council of Mutual Economic Aid on the Application of Isotopic Methods in Metallurgy, Katowice, Dec. 1970.

  3. K. Kimura, Bull. Chem. Soc. Japan, 33 (1960) 1038.

    Article  CAS  Google Scholar 

  4. K. Kimura, Bull. Chem. Soc. Japan, 34 (1961) 63.

    Article  CAS  Google Scholar 

  5. D. F. Peppard, E. P. Horwitz, G. W. Mason, J. Inorg. Nucl. Chem., 24 (1962) 429.

    Article  CAS  Google Scholar 

  6. L. N. Moskvin, V. I. Portnyagin, At. Energ. (USSR), 24 (1968) 568.

    Article  CAS  Google Scholar 

  7. T. S. Urbański, Thesis, Warsaw, 1964.

  8. D. F. Peppard, G. W. Mason, S. W. Moline, J. Inorg. Nucl. Chem., 5 (1957) 141.

    Article  CAS  Google Scholar 

  9. R. H. Bailes, TID-7508, 1955.

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Urbański, T.S. Extractive separation of a lanthanum tracer from preparations on a calcium carrier obtained from steel samples. J. Radioanal. Chem. 22, 13–19 (1974). https://doi.org/10.1007/BF02518088

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  • DOI: https://doi.org/10.1007/BF02518088

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