Abstract
A technique is described for the determination by instrumental neutron activation analysis of the zonal distribution of trace elements in diamond. Individual diamonds were irradiated and then dissolved in stages into 10 to 20 fractions in molten sodium nitrate. The activity of the material dissolved in each fraction was measured using a well-shielded Ge(Li) detector. Because of the small sample sizes involved, many elements typically found in diamond were below the limits of detection even though the experimental conditions were optimised for high sensitivity. The data obtained for a clear, a green and a coated diamond are given here to show the scope of the method. High levels of some elements in the outermost layers of all the diamonds are thought to have been due the implantation of surface contaminants during neutron irradiation. Removal of the outer few microns of irradiated diamonds before counting will avoid this source of error.
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Bibby, D.M. The determination of zonally distributed impurities in diamond by instrumental neutron activation analysis. J. Radioanal. Chem. 41, 101–113 (1977). https://doi.org/10.1007/BF02518045
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DOI: https://doi.org/10.1007/BF02518045