Skip to main content
SpringerLink
Log in

Redox substoichiometric determination of arsenic in biological materials by neutron activation analysis

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

A redox substoichiometry is proposed for an accurate and precise determination of arsenic. This method is based on the substoichiometric oxidation of trivalent arsenic to pentavalent with potassium bromate or ceric sulfate followed by the separation of these species by thionalide extraction of trivalent arsenic. It was applied to neutron activation analysis of arsenic in the NBS SRM Orchard Leaves and the Shark Powder. The results were obtained with an excellent accuracy and precision.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. KUDO, N. SUZUKI, J. Radioanal. Chem., 26 (1975) 327.

    CAS  Google Scholar 

  2. R. A. NADKARNI, J. Radioanal. Chem., 20 (1974) 139.

    Article  CAS  Google Scholar 

  3. H. L. POLAK, J. Radioanal. Chem., 9 (1971) 241.

    Article  CAS  Google Scholar 

  4. H. L. POLAK, H. DE GROOT, E. E. CHALLA, J. Radioanal. Chem., 13 (1973) 319.

    Article  CAS  Google Scholar 

  5. T. KAMBARA, J. SUZUKI, H. YOSHIOKA, T. NAKAMURA, Radioisotopes, 24 (1975) 319.

    Google Scholar 

  6. T. KAMBARA, J. SUZUKI, H. YOSHIOKA, T. NAKAMURA, Chemistry Lett., (1975) 927.

  7. T. KAMBARA, J. SUZUKI, H. YOSHIOKA, N. NAKAJIMA, J. Radioanal. Chem., 43 (1978) 139.

    Article  CAS  Google Scholar 

  8. Y. KANDA, N. SUZUKI, Radiochem. Radioanal. Lett. 39 (3) (1979) 221.

    CAS  Google Scholar 

  9. B. SJÖSTRAND, Anal. Chem., 36 (1964) 814.

    Article  Google Scholar 

  10. H. C. BEARD, L. A. LYERLY, Anal. Chem., 33 (1961) 1781.

    Article  CAS  Google Scholar 

  11. J. ROUZICKA, J. STARÝ, Talanta, 10 (1963) 685.

    Article  Google Scholar 

  12. A. ZEMAN, J. ROUZICKA, J. STARÝ, Talanta, 10 (1963) 456.

    Google Scholar 

  13. N. SUZUKI, K. KUDO, Anal. Chim. Acta, 32 (1965) 456.

    Article  CAS  Google Scholar 

  14. Y. DOKIYA, S. KUROSAWA, S. TODA, K. FUWA, Bull. Chem. Soc. Japan, 51 (1978) 3649.

    Article  CAS  Google Scholar 

  15. A. YASUI, C. TSUTSUMI, S. TODA, Agric. Biol. Chem., 42 (1978) 2139.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Research Institute of Police Science, Sanban-cho, Chiyoda-ku, 102, Tokyo, (Japan)

    Y. Kanda

  2. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, (Japan)

    N. Suzuki

Authors
  1. Y. Kanda
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Suzuki
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kanda, Y., Suzuki, N. Redox substoichiometric determination of arsenic in biological materials by neutron activation analysis. J. Radioanal. Chem. 54, 7–14 (1979). https://doi.org/10.1007/BF02517756

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02517756

Keywords

Search

Navigation