Skip to main content
SpringerLink
Log in

Radiotracer analysis of the physico-chemical state of trace elements in aqueous solutions

II. Electromigration method

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

The suitability of zone electrophoresis and of free-liquid electrophoresis for investigation of the physico-chemical forms of trace elements in aqueous solutions has been examined. Comparison of the electrophoretic mobilities of tervalent cerium determined by these two methods has demonstrated that adsorption of trace elements on the supporting medium renders zone electrophoresis unsuitable for investigation of hydrolytic and other reversible reactions of trace elements accompanied or preceded by significant adsorption. Free-liquid electrophoresis should be preferably used for this purpose as it is much less complicated by adsorption effects.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. E. STARIK, Osnovy Radiokhimiyi (Principles of Radiochemistry), Izd. Akad. Nauk SSSR, Moscow, 1959; 2nd, supplemented edn., Izd. Nauka, Leningrad, 1969.

  2. V. P. SHVEDOV (Ed.), Elektromigratsionnyi Metod v Fizikokhimicheskikh i Radiokhimicheskikh Issledovaniyiakh (Electromigration Method in Physicochemical and Radiochemical Investigation), Atomizdat, Moscow, 1971, pp. 39–42.

    Google Scholar 

  3. P. BENEŠ, V. MAJER, Trace chemistry of Aqueous Solutions. General Chemistry and Radiochemistry, Academia-Elsevier, in press.

  4. R. W. HENKENS, D. R. KALKWARF, Anal. Chem., 34 (1962) 830.

    Article  CAS  Google Scholar 

  5. I. E. STARIK, L. B. KOLYADIN, Zh. Neorg. Khim., 2 (1957) 1432.

    CAS  Google Scholar 

  6. V. P. SHVEDOV, A. V. STEPANOV, Radiokhimiyia, 1 (1959) 162.

    CAS  Google Scholar 

  7. H. LENGWEILER, W. BUSER, W. FEITKNECHT, Helv. Chim. Acta, 44 (1961) 805.

    Article  CAS  Google Scholar 

  8. S. K. SHUKLA, J. P. ADLOFF, J. Chromatog., 8 (1962) 501.

    Article  CAS  Google Scholar 

  9. P. BENEŠ, J. KUČERA, J. Inorg. Nucl. Chem., 33 (1971) 103.

    Article  Google Scholar 

  10. A. B. SHALINEC, A. V. STEPANOV, Radiokhimiyia, 13 (1971) 562.

    Google Scholar 

  11. B. GORSKI, H. KOCH, J. Inorg. Nucl. Chem., 31 (1969) 3565.

    Article  CAS  Google Scholar 

  12. A. B. SHALINEC, A. V. STEPANOV, Radiokhimiyia, 14 (1972) 280.

    Google Scholar 

  13. Yu. S. KOROTKIN, Radiokhimiyia, 15 (1973) 676, 766.

    CAS  Google Scholar 

  14. T. MOELER, J. Phys. Chem., 50 (1946) 242.

    Article  Google Scholar 

  15. P. L. SARMA, M. S. DAVIS, J. Inorg. Nucl. Chem., 29 (1967) 2607.

    Article  CAS  Google Scholar 

  16. P. BENEŠ, J. GLOS, A. GOSMAN, Radiochim. Acta, in press.

  17. J. KUČERA, P. BENEŠ, Chem. Listy, 65 (1971) 644.

    Google Scholar 

  18. H. W. HOYER, K. J. MYSELS, D. STIGTER, J. Phys. Chem., 58 (1954) 385.

    Article  CAS  Google Scholar 

  19. P. BENEŠ, J. GLOS, Radiochem. Radioanal. Lett., 37 (1979) 349.

    Google Scholar 

  20. Z. PUČAR, Anal. Chim. Acta, 17 (1957) 476.

    Article  Google Scholar 

  21. D. J. APERS, G. HARBOTTLE, Radiochim. Acta, 1 (1963) 188.

    CAS  Google Scholar 

  22. M. ISHIKAWA, Z. PUČAR, J. Radioanal. Chem., 11 (1972) 197.

    Article  CAS  Google Scholar 

Download references

Author information

Author notes

  1. J. Glos

    Present address: Research Institute of Nuclear Power Stations, CS 91931, Jaslovské Bohunice

Authors and Affiliations

  1. Department of Nuclear Chemistry, Technical University of Prague, Břehová 7, Prague 1, (Czechoslovakia)

    P. Beneš & J. Glos

Authors
  1. P. Beneš
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Glos
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Beneš, P., Glos, J. Radiotracer analysis of the physico-chemical state of trace elements in aqueous solutions. J. Radioanal. Chem. 52, 43–51 (1979). https://doi.org/10.1007/BF02517698

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02517698

Keywords

Search

Navigation