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Extraction of hydrobromic acid and uranyl bromide by trioctylphosphine oxide in cyclohexane and chloroform

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Abstract

The extraction of HBr and UO2Br2 by solutions of trioctylphosphine oxide in cyclohexane and chloroform was examined. From distribution data it was concluded that bisolvates HBr·2 TOPO and UO2Br2·2 TOPO were extracted, and the formation of CHCl3 TOPO complex is indicated. The corresponding concentrations quotients were calculated.

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References

  1. Y. MARCUS, A. S. KERTES, Ion Exchange and Solvent Extraction of Metal Complexes, Wiley-Interscience, New York, 1969.

    Google Scholar 

  2. YU. A. ZOLOTOV, B. Z. IOFA, L. K. CHUCHALIN, Ekstraktsija galogenidnykh kompleksov metallov, Nauka, Moscow, 1973.

    Google Scholar 

  3. A. I. MIKHAILICHENKO, Radiokhimiya, 12 (1970) 594.

    CAS  Google Scholar 

  4. J. J. BUCHER, T. J. CONCCHIOLI, E. R. HELD, J. A. LABINGER, B. A. SADBURY, R. M. DIAMOND, J. Inorg. Nucl. Chem., 37 (1975) 221.

    Article  CAS  Google Scholar 

  5. E. V. KOMAROV, M. F. PUSHLENKOV, Radiokhimiya, 3 (1961) 567, 575.

    CAS  Google Scholar 

  6. B. YA. SPIVAKOV, C. M. PETRUKHIN, YU. A. ZOLOTOV, Proc. Intern. Solvent Extraction Conf., Soc. of Chem. Ind., London, 1974, p. 35.

  7. Z. MARCZENKO, Kolorymetryczne oznaczanie pierwiastkow, WNT, Warsaw, 1968.

    Google Scholar 

  8. M. F. PUSHLENKOV, O. N. SHUVALOV, Radiokhimiya, 5 (1963) 551.

    Google Scholar 

  9. J. J. BUCHER, M. ZIRIN, R. C. LAUGEN, R. M. DIAMOND, J. Inorg. Nucl. Chem., 33 (1971) 3869.

    Article  CAS  Google Scholar 

  10. S. NISHIMURA, CH. H. KE, N. C. LI, J. Phys. Chem., (1968) 1297.

  11. C. KLOFUTAR, Š. PALJK, M. SENEGAČNIK, B. JERKOVIČ, J. Inorg. Nucl. Chem. 34 (1972) 2873.

    Article  Google Scholar 

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Author notes

  1. M. Mojski

    Present address: Department of Analytical Chemistry, Warsaw Technical University, Noakowskiego 3, 00-664, Warsaw, Poland

Authors and Affiliations

  1. Institut National des Sciences et Techniques Nucléaires, B. P. n0 6, 91190, Gif-sur-Yvette, (France)

    M. Mojski & C. Poitrenaud

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  1. M. Mojski
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  2. C. Poitrenaud
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Mojski, M., Poitrenaud, C. Extraction of hydrobromic acid and uranyl bromide by trioctylphosphine oxide in cyclohexane and chloroform. J. Radioanal. Chem. 29, 89–98 (1976). https://doi.org/10.1007/BF02516893

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  • DOI: https://doi.org/10.1007/BF02516893

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