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Synergistic extraction studies of uranium(VI) and plutonium(VI) with some β-diketones and heterocyclic N-oxides

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Abstract

The equilibrium constants for coordination of methyl substituted pyridine N-oxides with plutonium(VI) thenoyl trifluoroacetonate in chloroform (Ks) follow an order similar to those of the analogous uranium(VI) complexes indicating steric hindrance to bonding in the case of ortho substituted pyridine N-oxides. The extraction constants (k) of Pu(VI) chelates with various β-diketones are found to be only marginally higher than the values for the corresponding uranium(VI) chelates which is in conformity with the close similarity of the ionic radii of PuO 2+2 and UO 2+2 .

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References

  1. V. K. MANCHANDA, J. P. SHUKLA, M. S. SUBRAMANIAN, J. Inorg. Nucl. Chem., 36 (1974) 2595.

    Article  CAS  Google Scholar 

  2. H. IRVING, D. N. EDGINGTON, J. Inorg. Nucl. Chem., 20 (1961) 314.

    Article  CAS  Google Scholar 

  3. T. SEKINE, V. HASEGAWA, N. IHARA, J. Inorg. Nucl. Chem., 35 (1973) 3968.

    Article  CAS  Google Scholar 

  4. K. BATZAR, D. E. GOLDBERG, L. NEWMAN, J. Inorg. Nucl. Chem., 28 (1967) 1511.

    Article  Google Scholar 

  5. M. TANAKA, International Solvent Extraction Conference, J. G. GREGORY, B. EVANS, P. C. WESTON (Eds), Hague, 1972, p. 18.

  6. K. AKIBA, N. SUZUKI, H. ARANO, T. KANNO, J. Radioanal. Chem. 7 (1971) 203.

    Article  CAS  Google Scholar 

  7. J. P. SHUKLA, V. K. MANCHANDA, M. S. SUBRAMANIAN, J. Electroanalytical. Chem., 40 (1972) 431.

    Article  CAS  Google Scholar 

  8. J. P. SHUKLA, V. K. MANCHANDA, M. S. SUBRAMANIAN, J. Electroanalytical Chem., 50 (1974) 253.

    Article  CAS  Google Scholar 

  9. J. P. SHUKLA, V. K. MANCHANDA, M. S. SUBRAMANIAN (to be published).

  10. A. CASSOL, P. D. BERNARDO, R. PORTANOVA, L. MAGON, Inorg. Chim. Acta, 7 (1973) 353.

    Article  CAS  Google Scholar 

  11. S. M. WANG, W. R. WALKER, N. C. LI, J. Inorg. Nucl. Chem., 28 (1966) 875.

    Article  CAS  Google Scholar 

  12. W. R. WALKER, N. C. LI, J. Inorg. Nucl. Chem., 27 (1965) 2255.

    Article  CAS  Google Scholar 

  13. D. P. GRADDON, E. C. WATTON, J. Inorg. Nucl. Chem., 21 (1961) 49.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, 400085, Bombay, (India)

    V. K. Manchanda, J. P. Shukla & M. S. Subramanian

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  1. V. K. Manchanda
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  2. J. P. Shukla
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  3. M. S. Subramanian
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Manchanda, V.K., Shukla, J.P. & Subramanian, M.S. Synergistic extraction studies of uranium(VI) and plutonium(VI) with some β-diketones and heterocyclic N-oxides. J. Radioanal. Chem. 29, 69–75 (1976). https://doi.org/10.1007/BF02516891

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  • DOI: https://doi.org/10.1007/BF02516891

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