Abstract
The method of constant velocity supply of the radioactive labelled component into the system was used to study the kinetics of the isotope exchange Tl(I)-hydroxyquinolate-Tl(III)-hydroxyquinolate in chloroform. The second order exchange reaction with a halftime less than 1 min was determined in the range of concentrations 0.2–2·10−3 M of both components.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. GOSMAN, E. A. SOLDATOV, Dokl. Akad. Nauk SSSR, 167 (1966) 373.
E. SOLDATOV, A. GOSMAN, Z. Phys. Chem., 239 (1968) 422.
A. GOSMAN, Radiochem. Radioanal. Letters, 1 (1969) 345.
A. GOSMAN, J. SEDLÁČEK, Z. Phys. Chem., 240 (1969) 26.
A. GOSMAN, J. SEDLÁČEK, Z. Phys. Chem., 249 (1972) 161.
A. GOSMAN, Z. Phys. Chem., 251 (1972) 411.
E. HRADILOVÁ, Dipl. Thesis, Technical University of Prague, Prague, 1972.
A. GOSMAN, J. Radioanal. Chem., 30 (1976) 263.
J. STARÝ, Extrakoiya khelatov, Mir, Moskva, 1966.
V. V. NALIMOV, Primeneniye matematicheskoi statistiki pri analize veschestva, Fizmatgiz, Moskva, 1960.
V. M. SPIRIDONOV, A. A. LOPATKIN, Matematicheskaya obrabotka fiziko-chimicheskikh dannykh, Izd. MGU, Moskva, 1970.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sedláček, J., Gosman, A. & Podhájecký, P. Investigation of the kinetics of exchange reactions by the method of constant velocity supply of the labelled component into the system. J. Radioanal. Chem. 30, 285–291 (1976). https://doi.org/10.1007/BF02516639
Issue Date:
DOI: https://doi.org/10.1007/BF02516639