Skip to main content
Log in

The kinetics of the15N/14N isotopic exchange between nitric oxide and nitric acid

  • Stable Isotopes, Isotope Exchange
  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

The rate of the15N/14N isotopic exchange between NO−HNO3 at high nitric acid concentration (2–10M) have been measured. The experimental data were obtained by contacting nitric oxide at atmospheric pressure with nitric acid solution labelled with15N, in a glass contactor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. AXENTE, O. PIRINGER, J. Inorg. Nucl. Chem., 33 (1971) 665.

    Article  CAS  Google Scholar 

  2. D. AXENTE, O. PIRINGER, J. Inorg. Nucl. Chem., 34 (1972) 847.

    Article  CAS  Google Scholar 

  3. D. AXENTE, O. PIRINGER, J. Inorg. Nucl. Chem., 34 (1972) 1819.

    Article  CAS  Google Scholar 

  4. D. AXENTE, G. LACOSTE., J. MAHENC, J. Inorg. Nucl. Chem., 36 (1974) 2057.

    Article  CAS  Google Scholar 

  5. S. JORDAN, F. T. BONNER, Proc. Symp. Intern. Meeting on Isotope Effects in Physical and Chemical Process, Cluj, 1973 (in the press).

  6. W. SPINDEL, T. I. TAYLOR, J. Chem. Phys., 33 (1955) 981.

    Article  Google Scholar 

  7. K. G. DENBIGH, A. I. PRINCE, J. Chem. Soc., (1947) 790.

  8. H. A. McKAY, Nature, 142 (1938) 997.

    CAS  Google Scholar 

  9. H. A. McKAY, J. Am. Chem. Soc., 65 (1943) 702.

    Article  CAS  Google Scholar 

  10. G. M. BEGUN, L. L. BROWN, L. YEATTS, N. C. BRADLEY, E. F. JOSEPH, ORNL-2291, USA, 1957.

  11. M. J. STERN, L. N. KAUDER, W. SPINDEL J. Chem. Phys., 36 (1962) 762.

    Article  Google Scholar 

  12. W. L. JOLLY, The Inorganic Chemistry of Nitrogen, W. A. BENJAMIN (ed.), New York, Amsterdam, 1964, p. 78.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Axente, D., Piringer, O., Abrudean, M. et al. The kinetics of the15N/14N isotopic exchange between nitric oxide and nitric acid. J. Radioanal. Chem. 30, 233–244 (1976). https://doi.org/10.1007/BF02516635

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02516635

Keywords

Navigation