Abstract
The kinetics of the exchange of sulphate and chloride ions on the strongly basic anion exchanger Dowex 1X8, of different particle diameters is investigated. The diffusion coefficient values are calculated by two diferent methods, discussed in the light of the processes governing the exchange reactions encountered, and found to be mainly controlled by particle diffusion. The distribution behaviour of sulphate, sulphite, thiosulphate and sulphide between aqueous KCl solutions of different concentrations and a number of selected anion exchange resins is studied. The data are explained on the premises of the different interactions involved in both aqueous and resineous phases. The effect of the alkali metal chloride molarities in the aqueous phase (LiCl, NaCl and KCl) on the exchange behaviour of the different S-anions is also investigated. The results are interpreted in the light of the water—water interaction and the competition for hydration between the alkali metal cations and the exchanged S-anions.
Similar content being viewed by others
References
A. IGUCHI. Bull. Chem. Soc. Japan, 31 (1958) 600.
A. A. ABDEL-RASSOUL, A. ABDEL-AZIZ, H. F. ALY. J Inorg. Nucl. Chem., 31 (1969) 3043.
C. W. OWENS. Radiochem. Radioanal. Letters, 13 (1973) 325.
R. G. DESHPANDE. J. Chromat., 2 (1959) 117.
A. A. ABDEL-RASSOUL, H. FOUAD, A. ABDEL-AZIZ, S. WAHBA, S. MOHAMMED, Proc. 3rd Conf. Peaceful Uses Atomic Energy, 15 (1965) 445.
H. F. ALY M. M. ABDEL-HAMID. Microchem. J., 17 (1972) 215.
A. A. ABDEL-RASSOUL, A. ABDEL-AZIZ, H. F. ALY, Radiochim. Acta, 14 (1970) 113.
A. A. ABDEL-RASSOUL, A. ABDEL-AZIZ. Z. Anorg. Allgem. Chem., 330 (1964) 91.
M. ABDEL-HAMID EL-NASHABY, Studies on the chromatographic separation of different sulphur anions, M. Sc. Thesis, Cairo University, 1975.
R. M. BARRER, Diffusion in and through Solids, Cambridge University Press, New York, 1941, p. 29.
G. E. BOYD, A. W. ADAMSON, L. S. MYERS. J. Am. Chem. Soc., 69 (1947) 2836.
F. HELFFRICH, Ion Exchange, McGraw Hill, New York, 1962.
B. A. SOLDAN, G. E. BOYD. J. Am. Chem. Soc., 75 (1953) 6099.
B. CHU, D. C. WHITNEY, R. M. DIAMOND, J. Inorg. Nucl. Chem., 24 (1962) 1405.
D. C. WHITNEY, R. M. DIAMOND. Inorg. Chem., 2 (1963) 1264.
R. M. DIAMOND, J. Phys. Chem., 67 (1963) 2513.
C. H. JENSEN, R. M. DIAMOND, J. Phys. Chem., 76 (1964) 684.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Abdel-Rassoul, A.A., Aly, H.F., Borhan, A. et al. Kinetics and exchange behaviour of certain sulphur anions on strongly basic anion exchangers in aqueous KCl medium. J. Radioanal. Chem. 30, 93–102 (1976). https://doi.org/10.1007/BF02516621
Issue Date:
DOI: https://doi.org/10.1007/BF02516621