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Sorption of144Ce(III) and147Pm(III) on hydrated iron sesquioxide

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Abstract

The sorption of144Ce(III) and of147Pm(III) on hydrated iron sesquioxide suspension and the sorption of144Ce(III) on hydrated iron sesquioxide in a laboratory column were studied. The dependence of the sorption on pH and time, the sorption isotherm, the temperature-dependence of sorption, and the effects of ionic strength on sorption and desorption were determined under static conditions. The maximum sorptions of144Ce(III) and147Pm(III) were reached at pH=7.4 (Kd=8.9·105) and pH=9.1 (Kd=6.2·105), respectively.

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References

  1. C. B. Amphlett, Neorganicheskie ionity, Mir, Moscow, 1966, p. 113.

    Google Scholar 

  2. V. Veselý, V. Pekárek, Talanta, 19 (1972) 219.

    Article  Google Scholar 

  3. M. J. Fuller, Chromatogr. Rev., 14 (1071) 45.

    Article  Google Scholar 

  4. C. B. Amphlett, L. A. McDonald, M. J. Redman, J. Inorg. Nucl. Chem., 6 (1958) 236.

    Article  CAS  Google Scholar 

  5. N. B. Micheev, L. M. Micheeva, Dokl. Akad. Nauk SSSR, 158 (1964) 440.

    Google Scholar 

  6. A. Kozawa, J. Electrochem. Soc., 106 (1959) 552.

    CAS  Google Scholar 

  7. P. J. Anderson, Trans. Farady Soc., 54 (1957) 54.

    Google Scholar 

  8. A. K. Covington, T. Cressey, B. G. Lever, H. R. Thirsk, Trans. Faraday Soc., 58 (1972) 1975.

    Article  Google Scholar 

  9. F. Kepák, Coll. Czech. Chem. Commun., 31 (1966) 3051.

    Google Scholar 

  10. Z. Kolařík, Coll. Czech. Chem. Commun., 27 (1962) 938.

    Google Scholar 

  11. F. Kepák, J. Křivá, J. Inorg. Nucl. Chem., 33 (1971) 1741.

    Article  Google Scholar 

  12. F. M. Nelsen, F. T. Eggertsen, Anal. Chem., 30 (1958) 1387.

    Article  CAS  Google Scholar 

  13. F. Karas, in Ion Exchangers, their Properties and Application (Ed J. Šmid), SNTL Prague 1954, p. 583.

  14. Yu. V. Jegorov, Radiokhimiya, 14 (1971) 183.

    Google Scholar 

  15. T. Moeller, H. E. Kremers, Chem. Rev., 37 (1945) 97.

    Article  CAS  Google Scholar 

  16. A. Breeuwsma, J. Lyklema, Disc. Farady Soc. No. 52 Surface Chemistry of Oxides 1971, p. 276.

  17. V. Kellő, A. Tkáč, Physical Chemistry, ALFA, Bratislava 1969, p. 566.

    Google Scholar 

  18. H. A. Laitinen, Chemical Analysis, New York-Toronto-London, 1960, p. 169.

  19. R. Griessbach, Theory and Practice of Ion Exchange Inostr. Lit., Moscow, 1957, p. 195.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Nuclear Research, Řež, (Czechoslovakia)

    F. Kepák, M. Nuderová & J. Kaňka

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  1. F. Kepák
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  2. M. Nuderová
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  3. J. Kaňka
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Kepák, F., Nuderová, M. & Kaňka, J. Sorption of144Ce(III) and147Pm(III) on hydrated iron sesquioxide. J. Radioanal. Chem. 14, 325–333 (1973). https://doi.org/10.1007/BF02516596

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  • DOI: https://doi.org/10.1007/BF02516596

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