Journal of Radioanalytical Chemistry

, Volume 26, Issue 1, pp 73–77 | Cite as

Radiodünnschichtchromatographische Spurenbestimmung von Dithionsäure

  • S. Schönherr
  • H. Görz
  • G. Ackermann


A modified method of isotope dilution analysis is described for the determination of small amounts of dithionic acid (1–10 μg). The conditions for the setting up of the calibration curve are reported. The inactive dithionic acid is labelled with35S compound. After separation by thin layer chromatography on extremely thin layers the activity profiles of the spots are measured. The reduced maximal intensities are plotted against the amount of dithionic acid. The calibration curve is also valid for solutions containing up to 1M of sulphuric acid.


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  1. 1.
    R. SCHRADER, S. SCHÖNHERR, Naturwissenschaften, 48 (1961) 569.CrossRefGoogle Scholar
  2. 2.
    R. SCHRADER, S. SCHÖNHERR, Z. Anorg. Allg. Chemie, 331 (1964) 289.CrossRefGoogle Scholar
  3. 3.
    A. FISCHER, W. CLASSEN, Z. Angew. Chem., 35 (1922) 198.Google Scholar
  4. 4.
    S. GLASTONE, A. HICKLING, J. Chem. Soc., (1933) 5.Google Scholar
  5. 5.
    R. LANG, H. KURTENACKER, Z. Anal. Chem., 123 (1942) 89.Google Scholar
  6. 6.
    J. VEPŘEK-ŠISKA, K. ECKSCHLAGER, D. M. WAGNEROVÄ, Chem. Listy, 59 (1965) No. 12, 1479.Google Scholar
  7. 7.
    J. TÖLGYESSY, S. VARGA, Nuclear Analytical Chemistry, Vol. 2, Radioactive Indicators in Chemical Analysis, University Park Press, Baltimore-London-Tokyo, House of the Slovak Academy of Sciences, Bratislava, 1972.Google Scholar
  8. 8.
    G. ACKERMANN, E. WEBER, Talanta 15 (1968) 63.CrossRefGoogle Scholar
  9. 9.
    A. FAVA, G. PAJARO, Ann. Chim., 43 (1953) 502.Google Scholar
  10. 10.
    H. SEILER, G. ERLENMEYER, Helv. Chim. Acta, 47 (1953) 502.Google Scholar
  11. 11.
    G. BRAUER, Handbuch der präparativen anorganischen Chemie Bd. 1, Stuttgart, Enke-Verlag, 1960.Google Scholar

Copyright information

© Akadémiai Kiadó 1975

Authors and Affiliations

  • S. Schönherr
    • 1
  • H. Görz
    • 1
  • G. Ackermann
    • 1
  1. 1.Sektion Chemie der Bergakademie FreibergFreiberg (Sachsen)(DDR)

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